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用于不对称柔性超级电容器及催化还原硝基芳烃衍生物的双功能铜铁氧体-还原氧化石墨烯基纳米复合材料

Dual-Purpose CuFeO-rGO-Based Nanocomposite for Asymmetric Flexible Supercapacitors and Catalytic Reduction of Nitroaromatic Derivatives.

作者信息

Makkar Priyanka, Gogoi Debika, Roy Debmalya, Ghosh Narendra Nath

机构信息

Nano-materials Lab, Department of Chemistry, Birla Institute of Technology and Science, Pilani K K Birla Goa Campus, Pilani, Goa 403726, India.

Defence Materials and Stores Research & Development Establishment (DMSRDE) DRDO, Ministry of Defence, Government of India, PO DMSRDE, GT Road, Kanpur 208013, India.

出版信息

ACS Omega. 2021 Oct 19;6(43):28718-28728. doi: 10.1021/acsomega.1c03377. eCollection 2021 Nov 2.

Abstract

Energy storage and environmental pollution are two major global concerns in today's scenario. As a result of the momentous exhaustion of fossil fuels, the generation of energy from renewable sources is gaining immense importance. However, the irregular availability of energy from these renewable sources is the major encounter to achieve sustainable energy harvesting technology, yielding efficient but continuous and reliable energy supplies. Apart from the requirement of state-of-the-art heavy-duty technologies such as transportation, defense, etc., in the modern lifestyle to fulfill the demand for flexible electronic devices, the development of high-performance mechanically flexible all-solid-state supercapacitors is increasing massively. On the other hand, to cater to the need for accessibility of clean water for healthy lives, several technologies are evolving to treat wastewater and groundwater. Hence, the development of efficient catalysts for destroying water pollutants is an attractive approach. Considering these two crucial facets, in this paper, we have demonstrated the multifunctional features of a CuFeO-rGO nanocomposite, which was exploited to fabricate a high-performance mechanically flexible all-solid-state asymmetric supercapacitor and simultaneously used as an efficient but easily recoverable catalyst for the transformation of different nitroaromatic compounds. We have also demonstrated the conversion of trifluralin (a herbicide), which is present in the water body as a pollutant, to its corresponding amine derivatives, which can be utilized in the preparation of important pharmaceutical products.

摘要

在当今情况下,能量存储和环境污染是全球两大主要问题。由于化石燃料的大量消耗,可再生能源发电变得极为重要。然而,这些可再生能源供应的不稳定性是实现可持续能源采集技术的主要障碍,该技术需产生高效、持续且可靠的能源供应。除了现代生活方式中诸如交通运输、国防等领域对先进重型技术的需求,以满足对柔性电子设备的要求外,高性能机械柔性全固态超级电容器的研发也在大幅增加。另一方面,为满足健康生活对清洁水的需求,多种处理废水和地下水的技术不断涌现。因此,开发用于去除水中污染物的高效催化剂是一种有吸引力的方法。考虑到这两个关键方面,在本文中,我们展示了CuFeO-rGO纳米复合材料的多功能特性,该材料被用于制造高性能机械柔性全固态不对称超级电容器,同时用作将不同硝基芳香化合物转化的高效且易于回收的催化剂。我们还展示了水体中作为污染物存在的氟乐灵(一种除草剂)向其相应胺衍生物的转化,这些胺衍生物可用于制备重要的药品。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1792/8567344/a92f1b2ac67f/ao1c03377_0007.jpg

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