University of Novi Sad, Faculty of Technical Sciences, Trg Dositeja Obradovića 6, 21000, Novi Sad, Serbia.
Shale Gas Research Group, Institute of Hydrocarbon Recovery, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak Darul Ridzuan, Malaysia.
Chemosphere. 2022 Mar;291(Pt 3):132806. doi: 10.1016/j.chemosphere.2021.132806. Epub 2021 Nov 13.
One of the most significant chemical operations in the past century was the Haber-Bosch catalytic synthesis of ammonia, a fertilizer vital to human life. Many catalysts are developed for effective route of ammonia synthesis. The major challenges are to reduce temperature and pressure of process and to improve conversion of reactants produce green ammonia. The present review, briefly discusses the evolution of ammonia synthesis and current advances in nanocatalyst development. There are promising new ammonia synthesis catalysts of different morphology as well as magnetic nanoparticles and nanowires that could replace conventional Fused-Fe and Promoted-Ru catalysts in existing ammonia synthesis plants. These magnetic nanocatalyst could be basis for the production of magnetically induced one-step green ammonia and urea synthesis processes in future.
上个世纪最重要的化学操作之一是哈伯-博世催化合成氨,这是一种对人类生命至关重要的肥料。许多催化剂被开发出来以实现有效的氨合成途径。主要的挑战是降低工艺的温度和压力,并提高反应物的转化率以生产绿色氨。本综述简要讨论了氨合成的发展历程以及纳米催化剂开发的最新进展。目前有不同形态的很有前途的新型氨合成催化剂,以及磁性纳米颗粒和纳米线,它们可能取代现有氨合成工厂中传统的熔铁和促进钌催化剂。这些磁性纳米催化剂可能为未来磁诱导一步法绿色氨和尿素合成工艺的生产提供基础。