Nguyen Thi My Huyen, Lee Shin Kyu, Kim Sangmo, Bark Chung Wung
Department of Electrical Engineering, Gachon University, 1342 Seongnam-daero, Sujeong-gu, Seongnam-si, Gyeonggi-do 13120, South Korea.
School of Intelligent Mechatronics Engineering, Sejong University, Gwangjin-gu, Seoul 05006, South Korea.
ACS Appl Mater Interfaces. 2021 Dec 8;13(48):57609-57618. doi: 10.1021/acsami.1c18099. Epub 2021 Nov 22.
Flexible and self-powered photodetectors (PDs) have become one of the most popular topics, attracting researchers in the field of optoelectronic applications. In this study, for the first time, we demonstrate partial discharge detection in a practical environment with a prepared flexible device. Poly(vinylidene fluoride) (PVDF) is utilized as a highly transparent material in the UVC region, to create a flexible substrate with the antihumidity property. A detector that uses a mixed-halide perovskite (FAPbI)(MAPbBr) as the photoactive material is constructed in a vertical structure on the as-prepared hydrophobic PVDF substrate. The fabricated device exhibits good performance with a fast response speed ( = 82 ms, = 64 ms) and a high detectivity of 7.21 × 10 Jones at zero bias under 254 nm UV illumination, along with superior mechanical flexibility at various bending angles. Additionally, the air-exposure stability and reproducibility of the as-prepared device exhibit almost the original performance after 6 weeks of storage. For practical applications, we demonstrate a facile and sensitive detection for UVC leakage from a germicidal lamp and simulated a partial discharge system using our PD without energy consumption. These results indicate that this new approach may be useful and convenient for the detection of the partial discharge as well as for several practical applications.
柔性自供电光电探测器(PDs)已成为最热门的话题之一,吸引了光电应用领域的研究人员。在本研究中,我们首次展示了使用制备好的柔性器件在实际环境中进行局部放电检测。聚偏氟乙烯(PVDF)在UVC区域用作高透明材料,以制造具有防潮性能的柔性基板。在制备好的疏水性PVDF基板上以垂直结构构建了一种以混合卤化物钙钛矿(FAPbI)(MAPbBr)作为光活性材料的探测器。所制备的器件表现出良好的性能,在254 nm紫外光照下零偏压时具有快速响应速度(上升时间 = 82 ms,下降时间 = 64 ms)和7.21×10琼斯的高探测率,以及在各种弯曲角度下具有优异的机械柔韧性。此外,制备好的器件在空气暴露下的稳定性和可重复性在储存6周后几乎表现出原始性能。对于实际应用,我们展示了一种简便且灵敏的方法来检测杀菌灯的UVC泄漏,并使用我们的光电探测器模拟了一个无能耗的局部放电系统。这些结果表明,这种新方法对于局部放电检测以及一些实际应用可能是有用且方便的。