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论主-族元素键相互作用在超分子催化中的重要性。

On the Importance of Pnictogen and Chalcogen Bonding Interactions in Supramolecular Catalysis.

机构信息

Departament de Química, Universitat de les Illes Balears, Crta. de Valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain.

出版信息

Int J Mol Sci. 2021 Nov 21;22(22):12550. doi: 10.3390/ijms222212550.

DOI:10.3390/ijms222212550
PMID:34830432
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8623369/
Abstract

In this review, several examples of the application of pnictogen (Pn) (group 15) and chalcogen (Ch) bonding (group 16) interactions in organocatalytic processes are gathered, backed up with Molecular Electrostatic Potential surfaces of model systems. Despite the fact that the use of catalysts based on pnictogen and chalcogen bonding interactions is taking its first steps, it should be considered and used by the scientific community as a novel, promising tool in the field of organocatalysis.

摘要

在这篇综述中，收集了几个应用磷属（Pn）（第 15 族）和硫属（Ch）键（第 16 族）相互作用的例子，并用模型体系的分子静电势表面进行了支持。尽管基于磷属和硫属键相互作用的催化剂的使用才刚刚起步，但科学界应该将其视为有机催化领域的一种新颖、有前途的工具加以考虑和应用。

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