Li Na, Li Zhengyang, Wei Yujie
LNM, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, China.
School of Engineering Sciences, University of Chinese Academy of Sciences, Beijing 100049, China.
Nanomaterials (Basel). 2021 Oct 26;11(11):2859. doi: 10.3390/nano11112859.
Metastable cellular structures (MCSs) play a crucial role for the mechanical performance in concentrated alloys during non-equilibrium solidification process. In this paper, typifying the heterogeneous 316L stainless steel by laser additive manufacturing (LAM) process, we examine the microstructures in cellular interiors and cellular boundaries in detail, and reveal the interactions of dislocations and twins with cellular boundaries. Highly ordered coherent precipitates present along the cellular boundary, resulting from spinodal decomposition by local chemical fluctuation. The co-existences of precipitates and high density of tangled dislocations at cellular boundaries serve as walls for extra hardening. Furthermore, local chemical fluctuation in MCSs inducing variation in stacking fault energy is another important factor for ductility enhancement. These findings shed light on possible routines to further alter nanostructures, including precipitates and dislocation structures, by tailoring local chemistry in MCSs during LAM.
亚稳胞状组织(MCSs)在非平衡凝固过程中对高浓度合金的力学性能起着至关重要的作用。在本文中,通过激光增材制造(LAM)工艺制备典型的异质316L不锈钢,我们详细研究了胞状组织内部和胞界的微观结构,并揭示了位错和孪晶与胞界的相互作用。由于局部化学波动引起的调幅分解,在胞界处出现了高度有序的共格析出相。胞界处析出相和高密度缠结位错的共存起到了额外强化的作用。此外,MCSs中的局部化学波动引起堆垛层错能的变化是提高延展性的另一个重要因素。这些发现为通过在LAM过程中调整MCSs中的局部化学来进一步改变纳米结构(包括析出相和位错结构)提供了可能的途径。