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稻壳热解生物炭的应用:石灰浆体中反应活性的评估

Use of biochar from rice husk pyrolysis: assessment of reactivity in lime pastes.

作者信息

Morales Luisa F, Herrera Katherine, López Julián E, Saldarriaga Juan F

机构信息

Dept. of Civil and Environmental Engineering, Universidad de Los Andes, 1Este #19A-40, 111711, Bogotá, Colombia.

Environmental Engineering Program, Universidad de Medellín, Carrera 87 #30-65, 050026, Medellín, Colombia.

出版信息

Heliyon. 2021 Nov 18;7(11):e08423. doi: 10.1016/j.heliyon.2021.e08423. eCollection 2021 Nov.

Abstract

Biochar has unique properties such as its porous structure, specific surface area, and stable chemical properties. The rice husk is characterized by its high content of silica, and that during the pyrolysis process it generates a considerable amount of biochar that can be used in different processes. The aim of this work is to evaluate several biochars from the pyrolysis process in the reactivity of lime pastes. For this, biochar has been obtained at four different temperatures (450, 500, 550 and 600 °C), and they have been characterized by XRF, XRD, ICP-EOS, and particle size distribution, to determine their phases and their chemical composition. Biochar has been replaced in lime pastes in different proportions (5, 10, 15, 20, 25 and 30%), and exposed to different curing times (1, 3, 7, 14, 28, 56, 90 and 180 days). It has been found that all the replacements show reactivity within the lime pastes and that the percentage of 25% in all the biochar tested could be an adequate replacement.

摘要

生物炭具有独特的性质,如多孔结构、比表面积和稳定的化学性质。稻壳的特点是二氧化硅含量高,并且在热解过程中会产生大量可用于不同工艺的生物炭。这项工作的目的是评估热解过程中产生的几种生物炭对石灰浆反应活性的影响。为此,在四个不同温度(450、500、550和600℃)下制备了生物炭,并通过X射线荧光光谱仪(XRF)、X射线衍射仪(XRD)、电感耦合等离子体发射光谱仪(ICP - EOS)和粒度分布对其进行了表征,以确定其物相和化学成分。生物炭以不同比例(5%、10%、15%、20%、25%和30%)替代石灰浆,并暴露于不同的养护时间(1天、3天、7天、14天、28天、56天、90天和180天)。结果发现,所有替代物在石灰浆中均表现出反应活性,并且在所有测试的生物炭中,25%的替代比例可能是合适的。

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