Bugallo D, Langenberg E, Carbó-Argibay E, Varela Dominguez Noa, Fumega A O, Pardo V, Lucas Irene, Morellón Luis, Rivadulla F
Centro Singular de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS), Departamento de Química-Física, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain.
Department of Condensed Matter Physics, Institute of Nanoscience and Nanotechnology (IN2UB), University of Barcelona, 08020 Barcelona, Spain.
J Phys Chem Lett. 2021 Dec 16;12(49):11878-11885. doi: 10.1021/acs.jpclett.1c03418. Epub 2021 Dec 7.
Accessing the regime of coherent phonon propagation in nanostructures opens enormous possibilities to control the thermal conductivity in energy harvesting devices, phononic circuits, etc. In this paper we show that coherent phonons contribute substantially to the thermal conductivity of LaCoO/SrTiO oxide superlattices, up to room temperature. We show that their contribution can be tuned through small variations of the superlattice periodicity, without changing the total superlattice thickness. Using this strategy, we tuned the thermal conductivity by 20% at room temperature. We also discuss the role of interface mixing and epitaxial relaxation as an extrinsic, material dependent key parameter for understanding the thermal conductivity of oxide superlattices.
研究纳米结构中相干声子的传播机制为控制能量收集装置、声子电路等中的热导率开辟了巨大的可能性。在本文中,我们表明,直到室温,相干声子对LaCoO/SrTiO氧化物超晶格的热导率都有显著贡献。我们表明,通过超晶格周期的微小变化可以调节它们的贡献,而不改变超晶格的总厚度。利用这一策略,我们在室温下将热导率调节了20%。我们还讨论了界面混合和外延弛豫作为理解氧化物超晶格热导率的一个外在的、与材料相关的关键参数的作用。