P-Doped Ni/NiO Heterostructured Yolk-Shell Nanospheres Encapsulated in Graphite for Enhanced Lithium Storage.

The development of high-efficiency lithium-ion battery electrodes composed of recycled materials is crucial for the commercialization of retired batteries, but it remains a significant barrier. The usage and recycling of spent graphite are encouraged by the huge number of batteries that are going to be dismantled. Here, an anode made of phosphorus-doped Ni/NiO yolk-shell nanospheres embedded on wasted graphite is developed. Electroless deposition and a subsequent heat-treatment procedure are used to make it in a methodical manner. The internal vacuum space of the nanospheres mitigates volume expansion and facilitates Li diffusion, whereas the embedded metallic Ni and conductive graphite layer expedite charge transfer. The optimal reusable composite electrode is ecologically benign and has high specific capacities (724 mAh g at 0.1 A g ) as well as outstanding cycle stability (500 cycles). The unusual 3D sandwich-like arrangement with strong spent graphite, the yolk-shell hetero-structure, continuous electron/ion transport routes, and attractive structure stability all contribute to this degree of performance. Such a nanoscale design and engineering strategy not only provides a green recovery method for anode graphite, but also enlightens other nanocomposites to boost their lithium storage performance.