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具有热控表面附着力的石英晶体微天平,用于高效收集和传感细颗粒物。

Quartz crystal microbalance with thermally-controlled surface adhesion for an efficient fine dust collection and sensing.

作者信息

Jang Il Ryu, Jung Soon In, Lee Gunhee, Park Inyong, Kim Sang Bok, Kim Hoe Joon

机构信息

Department of Robotics Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST), Daegu 41988, Republic of Korea.

Department of Environmental Machinery, Environmental System Research Division, Korea Institute of Machinery and Materials (KIMM), Daejeon 34103, Republic of Korea.

出版信息

J Hazard Mater. 2022 Feb 15;424(Pt B):127560. doi: 10.1016/j.jhazmat.2021.127560. Epub 2021 Oct 20.

Abstract

The mass concentration of fine dust or particles acts as a standard measure to express the severity of air pollution. In connection with this, many related sensor technologies have been suggested for both indoor and outdoor uses. Among several technologies, the direct measurement of the dust mass using resonant platforms is the most preferable as it possesses multiple advantages including high sensitivity, low limit of detection, and a rapid response time. Such sensor performances directly rely on the adhesion quality between the sensor substrate and dust. In this work, we introduce a thermally controlled dust capturing scheme by integrating a polystyrene (PS) layer and microheater on quartz crystal microbalance (QCM). The Pt microheater can rapidly heat the sensor up to 100 °C, allowing a controlled switching between the soft and hard conditions of the PS film at a rapid rate. When the film is soft, the sensor can capture dust particle efficiently and we can calibrate the attached particle mass by measuring the resonance response. Compared to a bare QCM, our sensor used in this study exhibits 11 times larger detectable mass range. In addition, heated QCMs show a performance that is comparable to a high-cost particle sensing equipment such as an aerodynamic particle sizer and optical particle counter.

摘要

细粉尘或颗粒物的质量浓度是表示空气污染严重程度的标准指标。与此相关的是,已经提出了许多适用于室内和室外的相关传感技术。在多种技术中,使用谐振平台直接测量粉尘质量是最可取的,因为它具有高灵敏度、低检测限和快速响应时间等多种优点。这些传感器性能直接取决于传感器基板与粉尘之间的附着质量。在这项工作中,我们通过在石英晶体微天平(QCM)上集成聚苯乙烯(PS)层和微加热器,引入了一种热控粉尘捕获方案。铂微加热器可以将传感器快速加热到100°C,从而能够快速地在PS膜的软态和硬态之间进行可控切换。当膜处于软态时,传感器可以有效地捕获粉尘颗粒,并且我们可以通过测量共振响应来校准附着颗粒的质量。与裸QCM相比,本研究中使用的传感器的可检测质量范围大11倍。此外,加热后的QCM表现出与诸如空气动力学粒度分析仪和光学粒子计数器等高成本粒子传感设备相当的性能。

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