Time-Resolved Encryption via a Kinetics-Tunable Supramolecular Photochromic System.

With the advancement of forgery and decryption methods, conventional static encryption technology is becoming more and more powerless, which strongly demands the development of multistate anticounterfeiting materials as well as advanced multidimensional encryption strategies and technologies. Here a new strategy to realize time-resolved encryption based on a self-assembled supramolecular ternary complex is presented, which exhibits tunable dynamic photochromic features caused by the reversible photodimerization/cleavage reactions of the guest chromophores inside the cavity of cucurbit[8]uril (CB[8]). This supramolecular system shows excellent photochromic properties, including extremely rapid response time, high conversion rate, and product-stereoselectivity, etc. More importantly, the kinetics of the photoreaction can be modulated by simply varying the host-guest ratios in aqueous or quasi-solid phase, providing the material with finely tunable time-dependent features, which cannot only be employed in data processing with more extended information, but also construct confidential materials by time-resolved multidimensional encryption and dynamic anticounterfeiting. The strategic design of kinetics-tunable supramolecular photochromic materials may provide valuable guidance for the development of more advanced materials for information security.