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用于宽带微波吸收的空心珠状FeC/N掺杂碳纤维

Hollow Beaded FeC/N-Doped Carbon Fibers toward Broadband Microwave Absorption.

作者信息

Guo Rundong, Su Dong, Chen Fu, Cheng Yongzhi, Wang Xian, Gong Rongzhou, Luo Hui

机构信息

School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China.

School of Information Science and Engineering, Wuhan University of Science and Technology, Wuhan 430081, People's Republic of China.

出版信息

ACS Appl Mater Interfaces. 2022 Jan 19;14(2):3084-3094. doi: 10.1021/acsami.1c21272. Epub 2022 Jan 7.

Abstract

Microwave-absorbing materials have attracted enormous attention for electromagnetic (EM) pollution. Herein, hollow beaded FeC/N-doped carbon fibers (FeC/NCFs) were synthesized through convenient electrospinning and subsequent thermal treatment. The special hollow morphology of the samples is conducive to achieve lightweight and broadband microwave absorption properties. The thermal treatment temperatures exhibit a significant impact on conductivity and EM properties. The broadest effective absorption bandwidth (EAB) is 5.28 GHz at 2.16 mm when the thermal treatment temperature is 700 °C, and the EAB can cover 13.13 GHz with a tunable absorber thickness from 1.0 to 3.5 mm when the thermal treatment temperature is 750 °C. The excellent microwave absorption properties of the samples are due to the synergistic effect of impedance matching and strong EM energy attenuation abilities. Hence, the magnetic hollow beaded FeC/NCFs are expected to be an attractive candidate material as a lightweight and efficient microwave absorber in the future.

摘要

微波吸收材料因电磁(EM)污染问题而备受关注。在此,通过简便的静电纺丝及后续热处理合成了中空珠状FeC/N掺杂碳纤维(FeC/NCFs)。样品特殊的中空形态有利于实现轻质和宽带微波吸收性能。热处理温度对电导率和电磁性能有显著影响。当热处理温度为700℃时,在2.16 mm处最宽有效吸收带宽(EAB)为5.28 GHz;当热处理温度为750℃时,EAB可覆盖13.13 GHz,且吸收体厚度在1.0至3.5 mm之间可调。样品优异的微波吸收性能归因于阻抗匹配和强电磁能量衰减能力的协同效应。因此,磁性中空珠状FeC/NCFs有望成为未来一种有吸引力的轻质高效微波吸收候选材料。

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