MoS nanosheets vertically grown on CoSe hollow nanotube arrays as an efficient catalyst for the hydrogen evolution reaction.

Although the design and synthesis of efficient electrocatalysts for the hydrogen evolution reaction (HER) are highly desirable, severe challenges still need to be addressed. Herein, ultrathin MoS nanosheets were vertically grown on CoSe hollow nanotube arrays a simple three-step hydrothermal reaction by using carbon cloth (CC) as a substrate and were subsequently used as a highly efficient HER electrocatalyst (MoS@CoSe-CC hybrid). The MoS nanosheets uniformly self-assembled on conductive CoSe nanotube arrays exhibited a hierarchical and well-ordered structure. Such a unique structure may not only comprise more exposed active sites, but also enable fast electrolyte penetration and facilitate H/electron transportation to accelerate the reduction and evolution of H during the electrocatalytic process. As an HER electrocatalyst with a novel three-dimensional hierarchical structure, the MoS@CoSe-CC hybrid exhibited an outstanding catalytic HER performance with a small Tafel slope of 67 mV dec in alkaline media, while only requiring a low HER overpotential of 101 mV at 10 mA cm. Notably, the MoS@CoSe-CC hybrid also demonstrated exceptional electrochemical durability and structural stability even after 1000 cycles or 48 h of continuous electrolysis. Overall, this work presents a new approach for the design and synthesis of robust, highly active, and cost-effective electrocatalysts for hydrogen generation.