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纤维素醋酸酯在聚合物膜制备中的应用:综述。

Cellulose acetate in fabrication of polymeric membranes: A review.

机构信息

National Research Center on Membrane Technologies, Istanbul Technical University, Maslak, 34469, Istanbul, Turkey; Department of Applied Chemistry, Faculty of Chemistry, Kharazmi University, Tehran, 15719-14911, Iran; Environmental Engineering Department, Istanbul Technical University, Maslak, Istanbul, 34469, Turkey.

National Research Center on Membrane Technologies, Istanbul Technical University, Maslak, 34469, Istanbul, Turkey; Environmental Engineering Department, Istanbul Technical University, Maslak, Istanbul, 34469, Turkey.

出版信息

Chemosphere. 2022 May;295:133914. doi: 10.1016/j.chemosphere.2022.133914. Epub 2022 Feb 8.

Abstract

Developing biodegradable polymers to fabricate filtration membranes is one of the main challenges of membrane science and technology. Cellulose acetate (CA) membranes, due to their excellent film-forming property, high chemical and mechanical stability, high hydrophilicity, eco-friendly, and suitable cost, are extensively used in water and wastewater treatment, gas separation, and energy generation purposes. The CA is one of the first materials used to fabricate filtration membranes. However, in the last decade, the possibility of modification of CA to improve permeability and stability has attracted the researcher's attention again. This review is focused on the properties of cellulose derivatives and especially CA membranes in the fabrication of polymeric separation membranes in various applications such as filtration, gas separation, adsorption, and ion exchange membranes. Firstly, a brief introduction of CA properties and used molecular weights in the fabrication of membranes will be presented. After that, different configurations of CA membranes will be outlined, and the performance of CA membranes in several applications and configurations as the main polymer and as an additive in the fabrication of other polymer-based membranes will be discussed.

摘要

开发可生物降解聚合物来制造过滤膜是膜科学与技术的主要挑战之一。由于其出色的成膜性能、高化学和机械稳定性、高亲水性、环保以及合适的成本,醋酸纤维素 (CA) 膜广泛应用于水和废水处理、气体分离和能源生产等领域。CA 是最早用于制造过滤膜的材料之一。然而,在过去十年中,对 CA 进行改性以提高其渗透性和稳定性的可能性再次引起了研究人员的关注。本综述重点介绍了纤维素衍生物的特性,特别是 CA 膜在各种应用(如过滤、气体分离、吸附和离子交换膜)中用于制造聚合物分离膜的特性。首先,将简要介绍 CA 的特性以及在膜制备中使用的分子量。然后,将概述 CA 膜的不同结构,并讨论 CA 膜在几种应用和结构中的性能,作为主要聚合物以及作为其他基于聚合物的膜制备中的添加剂的性能。

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