通过氢氧化钠活化从树叶衍生的多孔生物质碳用于染料去除
Porous Biomass Carbon Derived from Leaves via NaOH Activation for Removal of Dye.
作者信息
Gao Wei
机构信息
College of Landscape Architecture, Changchun University, Changchun 130000, China.
出版信息
Materials (Basel). 2022 Feb 9;15(4):1285. doi: 10.3390/ma15041285.
(CM), is an important ornamental plant and has been widely cultivated all over the world. However, there are no reports on -based porous biomass carbon (CMBC). In this study, for the first time, CM leaves were used to generate porous biomass carbon via NaOH activation. The structures and surface characteristics were determined using scanning electron microscopy, N adsorption/desorption, TGA, FT-IR, X-ray diffraction, Raman and X-ray photoelectron spectra tests. CMBC has a large SSA (2716 m/g) and a total pore volume of 1.95 cm/g. To test the adsorption performance via adsorption experiments, the cationic and synthetic dye, malachite green (MG), was utilized as the adsorption model. The CMBC had a greatest adsorption capacity of 2622.9 mg/g at a pH value of 8 and had a fastest adsorption capacity of 1161.7 mg/g in the first 5 min. To explain MG adsorption into CMBC, the Freundlich isotherm and the pseudo-second-order kinetic model were used. The adsorption mechanism of MG was also investigated. After 10 cycles, the adsorption efficiency of CMBC to MG could still reach 85.3%. In summary, CMBC has excellent potential in dyeing wastewater pollution treatment.
(CM)是一种重要的观赏植物,已在世界各地广泛种植。然而,关于基于CM的多孔生物质碳(CMBC)尚无报道。在本研究中,首次使用CM叶片通过NaOH活化来制备多孔生物质碳。通过扫描电子显微镜、N吸附/脱附、热重分析(TGA)、傅里叶变换红外光谱(FT-IR)、X射线衍射、拉曼光谱和X射线光电子能谱测试来确定其结构和表面特性。CMBC具有较大的比表面积(2716 m²/g)和1.95 cm³/g的总孔体积。为了通过吸附实验测试其吸附性能,使用阳离子和合成染料孔雀石绿(MG)作为吸附模型。CMBC在pH值为8时最大吸附容量为2622.9 mg/g,在前5分钟内最快吸附容量为1161.7 mg/g。为了解释MG在CMBC中的吸附情况,使用了弗伦德利希等温线和伪二级动力学模型。还研究了MG的吸附机制。经过10个循环后,CMBC对MG的吸附效率仍可达到85.3%。总之,CMBC在印染废水污染处理方面具有优异的潜力。
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