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用于环境修复的导电聚合物/氧化锌基光催化剂:综述

Conducting polymers/zinc oxide-based photocatalysts for environmental remediation: a review.

作者信息

Jadoun Sapana, Yáñez Jorge, Mansilla Héctor D, Riaz Ufana, Chauhan Narendra Pal Singh

机构信息

Facultad de Ciencias Químicas, Departamento de Química Analítica e Inorgánica, Universidad de Concepción, 4070371 Edmundo Larenas 129, Concepción, Chile.

Department of Chemistry, Materials Research Laboratory, Jamia Millia Islamia, New Delhi, 110025 India.

出版信息

Environ Chem Lett. 2022;20(3):2063-2083. doi: 10.1007/s10311-022-01398-w. Epub 2022 Feb 19.

Abstract

The accessibility to clean water is essential for humans, yet nearly 250 million people die yearly due to contamination by cholera, dysentery, arsenicosis, hepatitis A, polio, typhoid fever, schistosomiasis, malaria, and lead poisoning, according to the World Health Organization. Therefore, advanced materials and techniques are needed to remove contaminants. Here, we review nanohybrids combining conducting polymers and zinc oxide for the photocatalytic purification of waters, with focus on in situ polymerization, template synthesis, sol-gel method, and mixing of semiconductors. Advantages include less corrosion of zinc oxide, less charge recombination and more visible light absorption, up to 53%.

摘要

获得清洁水对人类至关重要,但据世界卫生组织称,每年有近2.5亿人死于霍乱、痢疾、砷中毒、甲型肝炎、小儿麻痹症、伤寒、血吸虫病、疟疾和铅中毒等污染疾病。因此,需要先进的材料和技术来去除污染物。在此,我们综述了用于水的光催化净化的导电聚合物与氧化锌复合的纳米杂化物,重点介绍原位聚合、模板合成、溶胶-凝胶法以及半导体混合。其优点包括氧化锌的腐蚀较少、电荷复合较少以及可见光吸收增加,高达53%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29f1/8857745/c1eb9c4291d8/10311_2022_1398_Fig1_HTML.jpg

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