Sun Siyu, Ma Liangwei, Wang Jie, Ma Xiang, Tian He
Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China.
Natl Sci Rev. 2021 May 11;9(2):nwab085. doi: 10.1093/nsr/nwab085. eCollection 2022 Feb.
A set of red-light-excited, metal-free room-temperature phosphorescence (RTP) systems was constructed with brominated phenolsulfonephthaleine derivatives. The best metal-free RTP system has the reddest near-infrared (NIR) RTP emission (λ = 819 nm) with the highest phosphorescence quantum yield (Φ = 3.0%) so far identified. The RTP emission can be switched ON-OFF by adding acid and alkali alternately. A logic operation with half-subtractor function and dual-channel response (visible light emission/NIR RTP emission) was also constructed based on these properties.
利用溴化酚磺酞衍生物构建了一组红光激发的无金属室温磷光（RTP）体系。目前已鉴定出的最佳无金属RTP体系具有最红的近红外（NIR）RTP发射（λ = 819 nm）以及最高的磷光量子产率（Φ = 3.0%）。通过交替添加酸和碱，RTP发射可以实现开启-关闭。基于这些特性，还构建了具有半减法器功能和双通道响应（可见光发射/近红外RTP发射）的逻辑运算。
