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饮料中微塑料的微观调查:以啤酒、矿泉水和茶为例。

A microscopic survey on microplastics in beverages: the case of beer, mineral water and tea.

机构信息

College of Food Science & Engineering, Ocean University of China, 5 Yushan, Road, Qingdao 266003, China.

Laboratory for Marine Drugs and Bioproducts, Pilot National Laboratory for Marine Science and Technology (Qingdao), Qingdao 266237, China.

出版信息

Analyst. 2022 Mar 14;147(6):1099-1105. doi: 10.1039/d2an00083k.

Abstract

It has been reported that microplastics exist ubiquitously in aquatic and terrestrial environments. Microplastic surveys on diverse daily foods with high consumption possibly containing microplastics have essential implications in clarifying the contamination routes, health risk assessment, and thereby preventing food pollution. Given the dependence of microplastic pollution on the regional environment, production and transportation, it further remains an open question on the number, size distribution and type of microplastics in foods from different countries worldwide. Here, we show that daily drinks produced worldwide, including beer, mineral water and tea, are all polluted with microplastics without exception. The number of microplastics investigated in this work lies in the range of 20-80 mL for the beers, 10 mL for the bottled mineral water, and 200-500 g for the tea leaves. Quasi-spherical particles and irregular fragments dominate the shape of microplastics in beer and mineral water, whereas tea leaves carry numerous microplastic fibers. By identification through Raman spectroscopy, we observed the presence of polystyrene (PS) and polypropylene (PP) microplastics in beers, PP in bottled mineral water, and polyethylene (PE) and polyethylene terephthalate (PET) in tea leaves. Possible contamination sources include raw materials, atmosphere, and tools and containers that release microplastics. Given the facile adsorption of heavy metals and antibiotics to microplastics in beverages, public concern may arise regarding the accumulation of microplastics through the food chain and their synergetic harmful effect. Thus, our results should inspire further efforts that may contribute to the elimination and removal of microplastics from foods.

摘要

据报道,微塑料广泛存在于水和陆地环境中。对含有微塑料的各种日常高消费食品进行微塑料调查,对于阐明污染途径、进行健康风险评估以及防止食物污染具有重要意义。鉴于微塑料污染取决于区域环境、生产和运输,因此不同国家和地区的食品中微塑料的数量、大小分布和类型仍然是一个悬而未决的问题。在这里,我们表明,包括啤酒、矿泉水和茶在内的世界各地生产的日常饮料无一例外地受到微塑料的污染。在这项工作中调查的微塑料数量在啤酒中为 20-80 毫升,瓶装矿泉水中为 10 毫升,茶叶中为 200-500 克。准球形颗粒和不规则碎片是啤酒和矿泉水中小微塑料的主要形状,而茶叶中则携带大量微塑料纤维。通过拉曼光谱鉴定,我们观察到啤酒中存在聚苯乙烯(PS)和聚丙烯(PP)微塑料、瓶装矿泉水中存在 PP、茶叶中存在聚乙烯(PE)和聚对苯二甲酸乙二醇酯(PET)。可能的污染来源包括原材料、大气以及释放微塑料的工具和容器。鉴于饮料中重金属和抗生素容易吸附到微塑料上,公众可能会担心微塑料通过食物链的积累及其协同有害影响。因此,我们的研究结果应该激励进一步的努力,以帮助消除和去除食品中的微塑料。

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