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含可结晶嵌段共聚物的自组装:策略与应用

Self-Assembly of Copolymers Containing Crystallizable Blocks: Strategies and Applications.

作者信息

Shi Boyang, Shen Ding, Li Wei, Wang Guowei

机构信息

State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200433, P. R. China.

Department of Chemistry, Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai, 200433, P. R. China.

出版信息

Macromol Rapid Commun. 2022 Jul;43(14):e2200071. doi: 10.1002/marc.202200071. Epub 2022 Apr 9.

Abstract

The self-assembly of copolymers containing crystallizable blocks in solution has received increasing attention in the past few years. Various strategies including crystallization-driven self-assembly (CDSA) and polymerization-induced CDSA (PI-CDSA) have been widely developed. Abundant self-assembly morphologies are captured and advanced applications have been attempted. In this review, the synthetic strategies including the mechanisms and characteristics are highlighted and a survey on the advanced applications of crystalline nano-assemblies is collected. This review is hoped to depict a comprehensive outline for self-assembly of copolymers containing crystallizable blocks in recent years and to prompt the development of the self-assembly technology in interdisciplinary fields.

摘要

近年来,含可结晶嵌段的共聚物在溶液中的自组装受到了越来越多的关注。包括结晶驱动自组装(CDSA)和聚合诱导CDSA(PI-CDSA)在内的各种策略得到了广泛发展。人们捕获了丰富的自组装形态,并尝试了先进的应用。在这篇综述中,重点介绍了包括机理和特点在内的合成策略,并收集了关于结晶纳米组装体先进应用的综述。希望这篇综述能够描绘出近年来含可结晶嵌段共聚物自组装的全面概况,并推动自组装技术在跨学科领域的发展。

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