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用于氧还原反应的磷掺杂石墨烯电催化剂

Phosphorus-Doped Graphene Electrocatalysts for Oxygen Reduction Reaction.

作者信息

Zhan Xinxing, Tong Xin, Gu Manqi, Tian Juan, Gao Zijian, Ma Liying, Xie Yadian, Chen Zhangsen, Ranganathan Hariprasad, Zhang Gaixia, Sun Shuhui

机构信息

School of Chemistry and Material Science, Guizhou Normal University, Guiyang 550001, China.

Key Laboratory of Low-Dimensional Materials and Big data, Guizhou Minzu University, Guiyang 550025, China.

出版信息

Nanomaterials (Basel). 2022 Mar 29;12(7):1141. doi: 10.3390/nano12071141.

DOI:10.3390/nano12071141
PMID:35407259
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9000525/
Abstract

Developing cheap and earth-abundant electrocatalysts with high activity and stability for oxygen reduction reactions (ORRs) is highly desired for the commercial implementation of fuel cells and metal-air batteries. Tremendous efforts have been made on doped-graphene catalysts. However, the progress of phosphorus-doped graphene (P-graphene) for ORRs has rarely been summarized until now. This review focuses on the recent development of P-graphene-based materials, including the various synthesis methods, ORR performance, and ORR mechanism. The applications of single phosphorus atom-doped graphene, phosphorus, nitrogen-codoped graphene (P, N-graphene), as well as phosphorus, multi-atoms codoped graphene (P, X-graphene) as catalysts, supporting materials, and coating materials for ORR are discussed thoroughly. Additionally, the current issues and perspectives for the development of P-graphene materials are proposed.

摘要

开发具有高活性和稳定性的廉价且储量丰富的氧还原反应（ORR）电催化剂，对于燃料电池和金属空气电池的商业应用至关重要。人们在掺杂石墨烯催化剂方面付出了巨大努力。然而，迄今为止，关于磷掺杂石墨烯（P-石墨烯）用于ORR的进展很少被总结。本文综述聚焦于基于P-石墨烯材料的最新进展，包括各种合成方法、ORR性能和ORR机理。全面讨论了单磷原子掺杂石墨烯、磷氮共掺杂石墨烯（P，N-石墨烯）以及磷多原子共掺杂石墨烯（P，X-石墨烯）作为ORR催化剂、载体材料和涂层材料的应用。此外，还提出了P-石墨烯材料发展中当前存在的问题和前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/9572f8f186f1/nanomaterials-12-01141-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/649d34e01347/nanomaterials-12-01141-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/d2d848dbe4e0/nanomaterials-12-01141-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/7ddd6d7d8cbf/nanomaterials-12-01141-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/313b80528091/nanomaterials-12-01141-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/6bc951759247/nanomaterials-12-01141-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/c7712c2ae610/nanomaterials-12-01141-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/7db405cf2f05/nanomaterials-12-01141-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/fe8db3acb000/nanomaterials-12-01141-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/19e1a77825bc/nanomaterials-12-01141-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/9572f8f186f1/nanomaterials-12-01141-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/649d34e01347/nanomaterials-12-01141-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/d2d848dbe4e0/nanomaterials-12-01141-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/7ddd6d7d8cbf/nanomaterials-12-01141-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/313b80528091/nanomaterials-12-01141-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/6bc951759247/nanomaterials-12-01141-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/c7712c2ae610/nanomaterials-12-01141-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/7db405cf2f05/nanomaterials-12-01141-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/fe8db3acb000/nanomaterials-12-01141-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/19e1a77825bc/nanomaterials-12-01141-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a36/9000525/9572f8f186f1/nanomaterials-12-01141-g010.jpg

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