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杂原子掺杂石墨烯作为传感材料:一篇综述

Heteroatom-doped graphene as sensing materials: a mini review.

作者信息

Kaushal Sandeep, Kaur Manpreet, Kaur Navdeep, Kumari Vanita, Singh Prit Pal

机构信息

Department of Chemistry, Sri Guru Granth Sahib World University Fatehgarh Sahib Punjab India

出版信息

RSC Adv. 2020 Aug 4;10(48):28608-28629. doi: 10.1039/d0ra04432f. eCollection 2020 Aug 3.

Abstract

Graphene is one of the astounding recent advancements in current science and one of the most encouraging materials for application in cutting-edge electronic gadgets. Graphene and its derivatives like graphene oxide and reduced graphene oxide have emerged as significant nanomaterials in the area of sensors. Furthermore, doping of graphene and its derivatives with heteroatoms (B, N, P, S, I, Br, Cl and F) alters their electronic and chemical properties which are best suited for the construction of economical sensors of practical utility. This review recapitulates the developments in graphene materials as emerging electrochemical, ultrasensitive explosive, gas, glucose and biological sensors for various molecules with greater sensitivity, selectivity and a low limit of detection. Apart from the most important turn of events, the properties and incipient utilization of the ever evolving family of heteroatom-doped graphene are also discussed. This review article encompasses a wide range of heteroatom-doped graphene materials as sensors for the detection of NH, NO, HO, heavy metal ions, dopamine, bleomycinsulphate, acetaminophen, caffeic acid, chloramphenicol and trinitrotoluene. In addition, heteroatom-doped graphene materials were also explored for sensitivity and selectivity with respect to interfering analytes present in the system. Finally, the review article concludes with future perspectives for the advancement of heteroatom-doped graphene materials.

摘要

石墨烯是当代科学中令人震惊的最新进展之一,也是应用于前沿电子设备最具前景的材料之一。石墨烯及其衍生物,如氧化石墨烯和还原氧化石墨烯,已成为传感器领域重要的纳米材料。此外,用杂原子(B、N、P、S、I、Br、Cl和F)对石墨烯及其衍生物进行掺杂,会改变它们的电子和化学性质,这非常适合用于构建具有实际应用价值的经济型传感器。本综述概述了石墨烯材料作为新兴的电化学、超灵敏爆炸物、气体、葡萄糖和生物传感器在检测各种分子方面的进展,这些传感器具有更高的灵敏度、选择性和低检测限。除了最重要的事件转折外,还讨论了不断发展的杂原子掺杂石墨烯家族的性质和初步应用。这篇综述文章涵盖了广泛的杂原子掺杂石墨烯材料,这些材料可作为检测NH、NO、HO、重金属离子、多巴胺、博来霉素硫酸盐、对乙酰氨基酚、咖啡酸、氯霉素和三硝基甲苯的传感器。此外,还探讨了杂原子掺杂石墨烯材料对系统中存在的干扰分析物的灵敏度和选择性。最后,这篇综述文章以杂原子掺杂石墨烯材料的未来发展前景作为结尾。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8cf7/9055927/34ee249ec23e/d0ra04432f-f1.jpg

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