Lyu Ping, Fang Zhiqiang, Wang Xu, Huang Weibo, Zhang Rui, Sang Yingjie, Sun Pengfei
School of Civil Engineering, Qingdao University of Technology, Qingdao 266520, China.
Materials (Basel). 2022 Apr 1;15(7):2607. doi: 10.3390/ma15072607.
The mechanical strength, thermal stability, thermal performance, and microstructure of Qtech T26 blast mitigation polyurea (T26 polyurea) were studied using quasi-static and dynamic mechanical experiments, thermogravimetric experiments, differential scanning calorimetry (DSC), scanning electron microscopy (SEM) experiments, and contact explosion and non-contact explosion experiments with polyurea-coated reinforced concrete slabs. Additionally, the energy dissipation mechanism of the coating was analyzed. The blast mitigation ability and blast mitigation mechanism of T26 polyurea-coated reinforced concrete slabs were investigated by analyzing the macroscopic morphology of reinforced concrete slabs with or without coatings and the contact explosion simulation of polyurea-coated reinforced concrete slabs. The results showed that T26 polyurea exhibited a certain strain rate effect. Its initial thermal decomposition temperature reached 286 °C, and its thermal stability was good. After carbonization, carbon slag can form and adhere to the structural surface. The glass transition temperature Tgs of the soft segment was -44.9 °C, and the glass transition temperature Tgh of the hard segment was 36.5 °C, showing a certain amount of microphase separation morphology. After the explosion test, there was a small pit on the front surface of the coated reinforced concrete plate, and there was no damage on the back surface. The integrity of the plate was good. The uncoated reinforced concrete slab had a large crater on the front of the explosion surface, and the back of the explosion surface experienced explosion collapse, concrete crushing, and an overall loss of stability. The numerical simulation results showed that the failure mode of the coated plate was consistent with the test. The kinetic energy conversion rate of the uncoated reinforced concrete plate was 87.27%, and the kinetic energy conversion rate of the coated reinforced concrete plate was 95.36%. The T26 coating improved the kinetic energy conversion rate of the structure and improved the blast mitigation ability of the reinforced concrete plate structure.
采用准静态和动态力学试验、热重试验、差示扫描量热法(DSC)、扫描电子显微镜(SEM)试验以及对涂覆聚脲的钢筋混凝土板进行接触爆炸和非接触爆炸试验,研究了Qtech T26防爆聚脲(T26聚脲)的机械强度、热稳定性、热性能和微观结构。此外,还分析了涂层的能量耗散机制。通过分析有无涂层的钢筋混凝土板的宏观形态以及涂覆聚脲的钢筋混凝土板的接触爆炸模拟,研究了T26聚脲涂覆钢筋混凝土板的防爆能力和防爆机理。结果表明,T26聚脲表现出一定的应变率效应。其初始热分解温度达到286℃,热稳定性良好。碳化后,可形成碳渣并附着在结构表面。软段的玻璃化转变温度Tgs为-44.9℃,硬段的玻璃化转变温度Tgh为36.5℃,呈现出一定程度的微相分离形态。爆炸试验后,涂覆钢筋混凝土板正面有一个小坑,背面无损伤,板的完整性良好。未涂覆的钢筋混凝土板在爆炸面正面有一个大坑,爆炸面背面发生爆炸坍塌、混凝土破碎,整体失去稳定性。数值模拟结果表明,涂覆板的破坏模式与试验一致。未涂覆钢筋混凝土板的动能转化率为87.27%,涂覆钢筋混凝土板的动能转化率为95.36%。T26涂层提高了结构的动能转化率,提高了钢筋混凝土板结构的防爆能力。