Monoelemental two-dimensional boron nanomaterials beyond theoretical simulations: From experimental preparation, functionalized modification to practical applications.

During the past decade, there is an explosive growth of theoretical and computational studies on 2D boron-based nanomaterials. In terms of extensive predictions from theoretical simulations, borophene, boron nanosheets and 2D boron derivatives show excellent structural, electronic, photonic and nonlinear optical characteristics, and potential applications in a wide range of fields. In recent years, previous studies have reported the successful experimental preparations, superior properties, multi-functionalized modifications of various 2D boron and its derivatives, which show many practical applications in significant fields. To further promote the ever-increasing experimental studies, this present review systematically summarizes recent progress on experimental preparation methods, functionalized modification strategies and practical applications of 2D boron-based nanomaterials and multifunctional derivatives. Firstly, this review summarizes the experimental preparation methods, including molecular beam epitaxy, chemical vapor deposition, liquid-phase exfoliation, chemical reaction, and other auxiliary methods. Then, various strategies for functionalized modification are introduced overall, focusing on borophene derivatives, boron-based nanosheets, atom-introduced, chemically-functionalized borophene and boron nanosheets, borophene or boron nanosheet-based heterostructures, and other functionalized 2D boron nanomaterials. Subsequently, various potential applications are discussed in detail, involving energy storage, catalysis conversion, photonics, optoelectronics, sensors, bio-imaging, biomedicine therapy, and adsorption. We comment the state-of-the-art related studies concisely, and also discuss the current status, probable challenges and perspectives rationally. This review is timely, comprehensive, in-depth and highly attractive for scientists from multiple disciplines and scientific fields, and can facilitate further development of advanced functional low-dimensional nanomaterials and multi-functionalized systems toward high-performance practical applications in significant fields.