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不同热压压力和温度对直接甲醇燃料电池用钛网基膜电极组件性能的影响

Effect of Different Hot-Pressing Pressure and Temperature on the Performance of Titanium Mesh-Based MEA for DMFC.

作者信息

Wang Xingxing, Zhang Yujie, Zhu Yu, Lv Shuaishuai, Ni Hongjun, Deng Yelin, Yuan Yinnan

机构信息

School of Mechanical Engineering, Nantong University, Nantong 226019, China.

School of Rail Transportation, Soochow University, Suzhou 215131, China.

出版信息

Membranes (Basel). 2022 Apr 16;12(4):431. doi: 10.3390/membranes12040431.

Abstract

The hot-pressing process of the membrane electrode assembly (MEA) is one of the research hotspots in the field of the fuel cell. To obtain suitable titanium mesh-based MEA hot pressing process parameters, titanium mesh was used as electrode substrate material. The anode and cathode of MEA were prepared by the drip-coated method, and the titanium mesh-based MEA was prepared under different hot-pressing pressure and temperature, respectively. The performance of titanium mesh-based MEA was studied by morphological observation, elemental analysis, thickness measurement, single cell test and numerical fitting analysis. The results demonstrated that: with increasing hot-pressing pressure from 0 MPa to 10 MPa, the forming thickness of titanium mesh-based MEA is getting thin gradually, and the peak power density of titanium mesh-based MEA first increased and then gradually decreased; with increasing hot-pressing temperature from 115 °C to 155 °C, the peak power density of titanium mesh-based MEA enhanced at the beginning and then also gradually decreased. Under the premise of a hot-pressing time of 180 s and the optimal operating temperature of DMFC of 60 °C, the appropriate hot-pressing process conditions of titanium mesh-based MEA are a hot-pressing pressure of 5 MPa and a hot-pressing temperature of 135 °C. The results can provide a technological reference for the preparation of titanium mesh MEA for DMFC.

摘要

膜电极组件(MEA)的热压工艺是燃料电池领域的研究热点之一。为了获得合适的基于钛网的MEA热压工艺参数,采用钛网作为电极基底材料。MEA的阳极和阴极通过滴涂法制备,并分别在不同的热压压力和温度下制备基于钛网的MEA。通过形貌观察、元素分析、厚度测量、单电池测试和数值拟合分析等方法研究了基于钛网的MEA的性能。结果表明:随着热压压力从0MPa增加到10MPa,基于钛网的MEA的成型厚度逐渐变薄,基于钛网的MEA的峰值功率密度先增大后逐渐减小;随着热压温度从115℃升高到155℃,基于钛网的MEA的峰值功率密度开始时增强,随后也逐渐降低。在热压时间为180s且直接甲醇燃料电池(DMFC)最佳运行温度为60℃的前提下,基于钛网的MEA合适的热压工艺条件为热压压力5MPa和热压温度135℃。该结果可为DMFC用钛网MEA的制备提供工艺参考。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/42f6/9029175/b26ba8410413/membranes-12-00431-g001.jpg

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