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均相多金属层状双氢氧化物电催化剂实现高效海水氧化

High-performance seawater oxidation by a homogeneous multimetallic layered double hydroxide electrocatalyst.

作者信息

Yu Luo, Xiao Jiayong, Huang Chuqiang, Zhou Jianqing, Qiu Ming, Yu Ying, Ren Zhifeng, Chu Ching-Wu, Yu Jimmy C

机构信息

Department of Chemistry, The Chinese University of Hong Kong, Hong Kong SAR 999077, China.

Department of Physics, University of Houston, Houston, TX 77204.

出版信息

Proc Natl Acad Sci U S A. 2022 May 3;119(18):e2202382119. doi: 10.1073/pnas.2202382119. Epub 2022 Apr 27.

Abstract

SignificanceSeawater is one of the most abundant resources on Earth. Direct electrolysis of seawater is a transformative technology for sustainable hydrogen production without causing freshwater scarcity. However, this technology is severely impeded by a lack of robust and active oxygen evolution reaction (OER) electrocatalysts. Here, we report a highly efficient OER electrocatalyst composed of multimetallic layered double hydroxides, which affords superior catalytic performance and long-term durability for high-performance seawater electrolysis. To the best of our knowledge, this catalyst is among the most active for OER and it advances the development of seawater electrolysis technology.

摘要

意义

海水是地球上最丰富的资源之一。直接电解海水是一种可持续制氢的变革性技术,不会导致淡水短缺。然而,这项技术因缺乏强大且活性高的析氧反应(OER)电催化剂而受到严重阻碍。在此,我们报道了一种由多金属层状双氢氧化物组成的高效OER电催化剂,它为高性能海水电解提供了卓越的催化性能和长期耐久性。据我们所知,这种催化剂是OER活性最高的催化剂之一,它推动了海水电解技术的发展。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9cf0/9171373/af18b29ae4f0/pnas.2202382119fig01.jpg

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