State Key Laboratory of Silicon Materials, and School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China.
ACS Appl Mater Interfaces. 2022 May 11;14(18):21224-21231. doi: 10.1021/acsami.2c03431. Epub 2022 Apr 28.
Wearable thermoelectrics has attracted significant interest in recent years. Among them, rigid-structure thermoelectric generators (TEGs) were seldomly employed for wearable applications, although those exhibit significant advantages of high device output performance and impact resistance. Here, we report a type of rigid wearable TEGs (w-TEGs) without ceramic substrates made using a simple cutting-and-bonding method. Owing to the small contact area, the w-TEGs comprising 48-n/p-pairs can be well attached to the human body. The lack of ceramic substrates leaves more space in the height direction, which benefits the wearability in practical applications and high power density. We demonstrated that increasing the height of w-TEGs from 1.38 to 3.14 mm significantly improves the power density by a factor of 10. As a result, the maximum power densities of 7.9 μW cm and 43.6 μW cm for the w-TEGs were realized under the breezeless condition and a wind speed for normal walking, respectively. This work provides a feasible design solution for rigid-structure free-substrate w-TEGs with very high power density, which will speed up the research of wearable thermoelectrics.
近年来,可穿戴式热电材料引起了广泛关注。其中,刚性结构的热电发电机(TEG)很少应用于可穿戴设备,尽管它们具有较高的器件输出性能和抗冲击性的显著优势。在这里,我们报告了一种使用简单的切割和贴合方法制造的无陶瓷衬底的刚性可穿戴 TEG(w-TEG)。由于接触面积小,由 48 个 n/p 对组成的 w-TEG 可以很好地贴合人体。陶瓷衬底的缺失在高度方向上留出了更多空间,这有利于实际应用中的可穿戴性和高功率密度。我们证明,将 w-TEG 的高度从 1.38 毫米增加到 3.14 毫米,功率密度可提高 10 倍。因此,在无风条件下和正常步行时的风速下,w-TEG 的最大功率密度分别达到了 7.9 μW cm 和 43.6 μW cm。这项工作为具有非常高功率密度的无刚性结构基底 w-TEG 提供了一种可行的设计方案,将加快可穿戴式热电材料的研究。