酮的光诱导无金属α-硒化反应

Dalberto Bianca T, Schneider Paulo H

Instituto de Química, Universidade Federal do Rio Grande do Sul (UFRGS) PO Box 15003 91501-970 Porto Alegre RS Brazil

RSC Adv. 2020 Mar 11;10(18):10502-10509. doi: 10.1039/d0ra00802h.

Herein, we report an efficient photoinduced α-selenylation of ketones without metal, additives or under photosensitizer-free conditions, providing a green protocol using light energy to synthesize a variety of α-selenoketones. This new methodology proved to be a mild, simple and eco-friendly tool for the efficient synthesis of the desired products.

在此，我们报道了一种无需金属、添加剂或在无光敏剂条件下的酮的高效光诱导α-硒化反应，提供了一种利用光能合成多种α-硒代酮的绿色方法。这种新方法被证明是一种温和、简单且环保的工具，可用于高效合成所需产物。