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聚苯胺-氧化铁@氧化锌纳米复合材料:一种用于合成色烯并吡啶[]嘧啶衍生物的可磁分离且适用的催化剂。

A PANI-FeO@ZnO nanocomposite: a magnetically separable and applicable catalyst for the synthesis of chromeno-pyrido[]pyrimidine derivatives.

作者信息

Chaghari-Farahani Fatemeh, Abdolmohammadi Shahrzad, Kia-Kojoori Reza

机构信息

Department of Chemistry, East Tehran Branch, Islamic Azad University P. O. Box 18735-138 Tehran Iran

出版信息

RSC Adv. 2020 Apr 21;10(26):15614-15621. doi: 10.1039/d0ra01978j. eCollection 2020 Apr 16.

Abstract

We report herein green, practical, PANI-FeO@ZnO-nanocomposite-catalyzed cyclocondensation reactions involving 4-aminocoumarin, 1,3-dimethylbarbituric acid, and aromatic aldehydes in an aqueous medium at room temperature to synthesize 9,11-dimethyl-7-aryl-6-chromeno[3',4':5,6]pyrido[2,3-]pyrimidine-6,8,10(9,11)triones. This research aims to provide an applicable and high-yield protocol that follows the principles of green chemistry, with the use of water as an environmentally benign medium and the PANI-FeO@ZnO nanocomposite as a magnetically recoverable catalyst.

摘要

我们在此报告,在室温下的水性介质中,绿色、实用的聚苯胺-氧化亚铁@氧化锌纳米复合材料催化4-氨基香豆素、1,3-二甲基巴比妥酸和芳香醛之间的环缩合反应,以合成9,11-二甲基-7-芳基-6-色烯并[3',4':5,6]吡啶并[2,3-]嘧啶-6,8,10(9,11)三酮。本研究旨在提供一种遵循绿色化学原则的适用且高产率的方案,使用水作为环境友好型介质,聚苯胺-氧化亚铁@氧化锌纳米复合材料作为可磁回收催化剂。

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