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一种用于中压/4-羟基-2,2,6,6-四甲基哌啶氧化物流动电池中石墨毡电极的新型改性方法。

A new modification method for graphite felt electrodes in a MV/4-HO-TEMPO flow battery.

作者信息

Li Xinyu, Huang Chengde

机构信息

Department of Applied Chemistry, School of Chemical Engineering and Technology, Tianjin University Tianjin 300072 P. R. China

出版信息

RSC Adv. 2020 Feb 11;10(11):6333-6341. doi: 10.1039/c9ra10966h. eCollection 2020 Feb 7.

Abstract

Using graphite felt as the support body, reduced graphene oxide (rGO) is grown on the surface of carbon fibers by the hydrothermal reduction method, and the modified graphite felt was used as an electrode material and studied in a methyl viologen (MV)/4-hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl (4-HO-TEMPO) redox flow battery. This paper aims to solve the insufficient adhesion of the dip-coating method by simple, effective and low-cost means and provides a possibility for large-scale production and application; the new modification method increases the reaction area and performance of the electrode, resulting in high current density and improved battery performance, and in the current density of 60 mA cm, the battery provides 97.39% theoretical capacity, which has practical significance for battery configurations.

摘要

以石墨毡为支撑体,通过水热还原法在碳纤维表面生长还原氧化石墨烯(rGO),并将改性后的石墨毡用作电极材料,在甲基紫精(MV)/4-羟基-2,2,6,6-四甲基哌啶-1-氧基(4-HO-TEMPO)氧化还原液流电池中进行研究。本文旨在通过简单、有效且低成本的方式解决浸涂法附着力不足的问题,并为大规模生产和应用提供可能性;新的改性方法增加了电极的反应面积和性能,从而实现了高电流密度并改善了电池性能,在60 mA cm的电流密度下,该电池提供了97.39%的理论容量,这对电池配置具有实际意义。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ba0f/9049689/24462cd50893/c9ra10966h-f1.jpg

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