铑（III）催化的二氢吲哚与芳基硅烷的C-7芳基化反应：C-H活化
Rh(iii)-catalyzed C-7 arylation of indolines with arylsilanes C-H activation.
作者信息
Luo Haiqing, Xie Qi, Sun Kai, Deng Jianbo, Xu Lin, Wang Kejun, Luo Xuzhong
机构信息
Department of Chemistry & Chemical Engineering, Gannan Normal University Ganzhou 341000 China
出版信息
RSC Adv. 2019 Jun 10;9(32):18191-18195. doi: 10.1039/c9ra04142g.
Abstract
Site-selective synthesis of C-7 arylated indolines has been achieved oxidative arylation of indolines with arylsilanes under Rh(iii)-catalyzed C-H activation of indolines by using CuSO as a co-oxidant. This transformation has been explored for a wide range of substrates under mild conditions.
摘要
通过使用硫酸铜作为共氧化剂，在铑（III）催化的吲哚啉C-H活化反应中，实现了吲哚啉与芳基硅烷的氧化芳基化反应，从而实现了C-7芳基化吲哚啉的位点选择性合成。在温和条件下，已对多种底物进行了这种转化反应的探索。
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