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用对氨基苯磺酸处理的羊毛织物的热稳定性、疏水性、抗紫外线辐射性能和抗菌性能增强。

Enhanced thermal stability, hydrophobicity, UV radiation resistance, and antibacterial properties of wool fabric treated with -aminobenzenesulphonic acid.

作者信息

Hassan Mohammad Mahbubul

机构信息

Bioproduct and Fibre Technology Team, AgResearch Limited 1365 Springs Road, Lincoln Christchurch 7647 New Zealand

出版信息

RSC Adv. 2020 May 5;10(30):17515-17523. doi: 10.1039/d0ra02267e.

DOI:10.1039/d0ra02267e
PMID:35515614
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9053736/
Abstract

Wool fibre is a popular fibre for the manufacture of apparel and floor coverings, but it does not have adequate thermal stability, antistatic, UV resistance, and antibacterial properties that are required for some applications, such as outerwear and hospital gowns. In this work, a wool fabric was treated with -aminobenzenesulphonic acid (ABSA) by the oxidative polymerisation method and its effect on the thermal stability, UV radiation resistance, electrical conductivity and antibacterial properties of the treated fabric was systematically evaluated. It was found that the ABSA treatment had synergistic effects on the various functional properties of the treated fabric. The ABSA treatment not only made the fabric antibacterial but also enhanced its UV radiation absorption capability, surface hydrophobicity, electro-conductivity, tensile strength, and thermal stability. The maximum degradation temperature of the wool fibre increased from 339.5 °C to 349.6 °C and the UV-B transmission through the fabric at 290 nm reduced to 1.5%. The surface hydrophobicity of the treated fabric samples also improved as the surface contact angle of the fabric increased from 119.5° for the untreated to 131.7° for the fabric treated with 4% ABSA. The surface electrical resistance decreased from 1200 × 10 to 484 × 10 Ohm cm, and the treated fabric also showed excellent antibacterial activity against and . The developed treatment could be used in the textile industry as an energy-efficient process for the multi-functionalisation of wool and other polyamide fibres.

摘要

羊毛纤维是用于制造服装和地板覆盖物的一种流行纤维,但它不具备某些应用(如户外服装和医院病号服)所需的足够热稳定性、抗静电性、抗紫外线和抗菌性能。在这项工作中,采用氧化聚合方法用对氨基苯磺酸(ABSA)处理羊毛织物,并系统评估了其对处理后织物的热稳定性、抗紫外线辐射性能、导电性和抗菌性能的影响。发现ABSA处理对处理后织物的各种功能特性具有协同作用。ABSA处理不仅使织物具有抗菌性,还增强了其紫外线辐射吸收能力、表面疏水性、导电性、拉伸强度和热稳定性。羊毛纤维的最大降解温度从339.5℃提高到349.6℃,在290nm处通过织物的紫外线B透过率降低到1.5%。处理后织物样品的表面疏水性也有所改善,织物的表面接触角从未处理时的119.5°增加到用4%ABSA处理的织物的131.7°。表面电阻从1200×10降低到484×10欧姆厘米,并且处理后的织物对[具体菌种1]和[具体菌种2]也表现出优异的抗菌活性。所开发的处理方法可作为一种节能工艺用于纺织工业中羊毛和其他聚酰胺纤维的多功能化处理。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/c0345223ac3d/d0ra02267e-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/540fa83dbf74/d0ra02267e-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/090b67472a00/d0ra02267e-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/fe5596147adb/d0ra02267e-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/cef3c6c7ce7a/d0ra02267e-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/ad149177b5a4/d0ra02267e-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/8bd16795f83a/d0ra02267e-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/c0345223ac3d/d0ra02267e-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/540fa83dbf74/d0ra02267e-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/090b67472a00/d0ra02267e-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/fe5596147adb/d0ra02267e-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/cef3c6c7ce7a/d0ra02267e-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/ad149177b5a4/d0ra02267e-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/8bd16795f83a/d0ra02267e-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1820/9053736/c0345223ac3d/d0ra02267e-f6.jpg

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