Zadmard Reza, Hokmabadi Fahimeh, Jalali Mohammad Reza, Akbarzadeh Ali
Chemistry and Chemical Engineering Research Center of Iran Iran
RSC Adv. 2020 Sep 3;10(54):32690-32722. doi: 10.1039/d0ra05707j. eCollection 2020 Sep 1.
The combination of supramolecular chemistry and polymer sciences creates a great possibility to afford calixarene-based polymers offering unique features and applications. The enhancement of calixarene's versatility in this manner has made chemists better able to achieve different objectives in host-guest chemistry. The calixarene-based polymers can be divided into covalent polymers and supramolecular polymers regarding the interactions. Although there are several studies available on the calixarene-based supramolecular polymers, there is a paucity of studies on the calixarene-based covalent polymers. In this paper, the most recent developments and applications of the calixarene-based covalent polymers in the last two decades have been reviewed. We have particularly focused on the polymers, including those where the calixarene molecules have been used as macromonomers and polymerize through covalent bonds. Moreover, covalent polymers or solid supports functionalized with calixarenes are highlighted as well.
超分子化学与聚合物科学的结合为制备具有独特特性和应用的杯芳烃基聚合物创造了巨大的可能性。以这种方式增强杯芳烃的多功能性，使化学家能够更好地在主客体化学中实现不同的目标。基于相互作用，杯芳烃基聚合物可分为共价聚合物和超分子聚合物。尽管有几项关于杯芳烃基超分子聚合物的研究，但关于杯芳烃基共价聚合物的研究却很少。本文综述了近二十年来杯芳烃基共价聚合物的最新进展和应用。我们特别关注了这些聚合物，包括那些将杯芳烃分子用作大分子单体并通过共价键聚合的聚合物。此外，用杯芳烃官能化的共价聚合物或固体支持物也受到了关注。
