Ren Long, Xu Bin, Wang Guodong, Yin Xiaoshuang, Liu Ying, Yang Wenzhong, Chen Yun
School of Chemistry and Molecular Engineering, Nanjing Tech University No. 30 Puzhu Road (S) Nanjing 211816 China
Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environmental of the People's Republic of China No. 8 Jiangwangmiao Street Nanjing 210042 China.
RSC Adv. 2020 Oct 26;10(64):39130-39136. doi: 10.1039/d0ra08339a. eCollection 2020 Oct 21.
In this study, antimony doped tin oxide loaded reduced graphene oxide (ATO-RGO) nanocomposites were synthesized a facile hydrothermal approach. As a typical N-type semiconductor, the ATO in the composite can enhance the conductivity between graphene sheets, thus improving the specific capacitance and electrosorption performance. Under the optimal conditions, the largest surface area was 445.2 m g when the mass content of ATO in the nanocomposite was 20 wt%. The synthesized optimal ATO-RGO electrode displayed excellent specific capacity (158.2 F g) and outstanding electrosorptive capacity (8.63 mg g) in sodium chloride solution, which were much higher than the corresponding results of pristine graphene (74.3 F g and 3.98 mg g). At the same applied voltage, electrosorption capacity and charge efficiency of the ATO-RGO (20 wt%) material were better than those of reported carbon materials in recent years.
在本研究中,采用简便的水热法合成了锑掺杂的氧化锡负载还原氧化石墨烯(ATO-RGO)纳米复合材料。作为典型的N型半导体,复合材料中的ATO可增强石墨烯片层间的导电性,从而提高比电容和电吸附性能。在最佳条件下,当纳米复合材料中ATO的质量含量为20 wt%时,最大表面积为445.2 m²/g。合成的最佳ATO-RGO电极在氯化钠溶液中表现出优异的比容量(158.2 F/g)和出色的电吸附容量(8.63 mg/g),远高于原始石墨烯的相应结果(74.3 F/g和3.98 mg/g)。在相同的施加电压下,ATO-RGO(20 wt%)材料的电吸附容量和电荷效率优于近年来报道的碳材料。