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用于高性能超级电容器的电极的超细氧化钌量子点/还原氧化石墨烯复合材料

Ultra-Fine Ruthenium Oxide Quantum Dots/Reduced Graphene Oxide Composite as Electrodes for High-Performance Supercapacitors.

作者信息

Zhao Jie, Zhang Jianmin, Yin Hang, Zhao Yuling, Xu Guangxu, Yuan Jinshi, Mo Xiaoyao, Tang Jie, Wang Fengyun

机构信息

College of Physics, Qingdao University, No. 308 Ningxia Road, Qingdao 266071, China.

National Engineering Research Center for Intelligent Electrical Vehicle Power System, College of Mechanical and Electrical Engineering, Qingdao University, No. 308 Ningxia Road, Qingdao 266071, China.

出版信息

Nanomaterials (Basel). 2022 Apr 4;12(7):1210. doi: 10.3390/nano12071210.

Abstract

This study synthesized ultra-fine nanometer-scaled ruthenium oxide (RuO) quantum dots (QDs) on reduced graphene oxide (rGO) surface by a facile and rapid microwave-assisted hydrothermal approach. Benefiting from the synergistic effect of RuO and rGO, RuO/rGO nanocomposite electrodes showed ultra-high capacitive performance. The impact of different RuO loadings in RuO/rGO nanocomposite on their electrochemical performance was investigated by various characterizations. The composite RG-2 with 38 wt.% RuO loadings exhibited a specific capacitance of 1120 F g at 1 A g. In addition, it has an excellent capacity retention rate of 84 % from 1A g to 10 A g, and excellent cycling stability of 89% retention after 10,000 cycles, indicating fast ion-involved redox reactions on the nanocomposite surfaces. These results illustrate that RuO/rGO composites prepared by this facile process can be an ideal candidate electrode for high-performance supercapacitors.

摘要

本研究通过简便快速的微波辅助水热法在还原氧化石墨烯(rGO)表面合成了超细纳米级氧化钌(RuO)量子点(QDs)。得益于RuO和rGO的协同效应,RuO/rGO纳米复合电极表现出超高的电容性能。通过各种表征研究了RuO/rGO纳米复合材料中不同RuO负载量对其电化学性能的影响。RuO负载量为38 wt.%的复合RG-2在1 A g时表现出1120 F g的比电容。此外,它在1A g至10 A g范围内具有84%的优异容量保持率,在10000次循环后具有89%保持率的优异循环稳定性,表明纳米复合材料表面存在快速的离子参与氧化还原反应。这些结果表明,通过这种简便工艺制备的RuO/rGO复合材料可以成为高性能超级电容器的理想候选电极。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7768/9000793/941d0a3daf1a/nanomaterials-12-01210-g001.jpg

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