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使用高导电性中性树胶电解质的全固态超级电容器。

All-solid-state supercapacitors using a highly-conductive neutral gum electrolyte.

作者信息

Yu Nengsheng, Wang Xiaona, Zhang Silan, Zeng Sha, Zhang Yongyi, Di Jiangtao, Li Qingwen

机构信息

Key Laboratory of Multifunctional Nanomaterials and Smart Systems, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences Suzhou 215123 China

Nano Science and Technology Institute, University of Science and Technology of China Suzhou 215123 China.

出版信息

RSC Adv. 2019 Mar 12;9(15):8169-8174. doi: 10.1039/c9ra00494g.

Abstract

Recently, the development of safe, stable, and long-life supercapacitors has attracted considerable interest driven by the fast-growth of flexible wearable devices. Herein, we report an MnO-based symmetric all-solid-state supercapacitor, using a neutral gum electrolyte that was prepared by embedding aqueous sodium sulfate solution in a biopolymer xanthan gum. Resulting from the high ion conductivity 1.12 S m, good water retention, and high structure adaption of such gum electrolyte, the presently described supercapacitor showed high electrochemical performance with a specific capacitance of 347 F g at 1 A g and an energy density of 24 μW h cm The flexible supercapacitor possesses excellent reliability and achieves a retaining capacitance of 82% after 5000 cycles. In addition, the as-prepared supercapacitor demonstrated outstanding electrochemical stability at temperatures between -15 °C to 100 °C.

摘要

近年来,随着柔性可穿戴设备的快速发展,安全、稳定且寿命长的超级电容器的开发引起了广泛关注。在此,我们报道了一种基于MnO的对称全固态超级电容器,它使用了一种中性胶状电解质,该电解质是通过将硫酸钠水溶液嵌入生物聚合物黄原胶中制备而成。由于这种胶状电解质具有高离子电导率1.12 S/m、良好的保水性和高结构适应性,目前所描述的超级电容器表现出高电化学性能,在1 A/g时比电容为347 F/g,能量密度为24 μW h/cm²。该柔性超级电容器具有出色的可靠性,在5000次循环后保持电容为82%。此外,所制备的超级电容器在-15°C至100°C的温度范围内表现出出色的电化学稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ab6b/9061702/eed802529c30/c9ra00494g-f1.jpg

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