以KI为碘源、空气中的O为氧化剂，漆酶高效且可持续催化α-取代酚的碘化反应。
Efficient and sustainable laccase-catalyzed iodination of -substituted phenols using KI as iodine source and aerial O as oxidant.
作者信息
Sdahl Mark, Conrad Jürgen, Braunberger Christina, Beifuss Uwe
机构信息
Bioorganische Chemie, Institut für Chemie, Universität Hohenheim Garbenstr. 30 Stuttgart D-70599 Germany
出版信息
RSC Adv. 2019 Jun 21;9(34):19549-19559. doi: 10.1039/c9ra02541c. eCollection 2019 Jun 19.
Abstract
The laccase-catalyzed iodination of -hydroxyarylcarbonyl- and -hydroxyarylcarboxylic acid derivatives using KI as iodine source and aerial oxygen as the oxidant delivers the corresponding iodophenols in a highly efficient and sustainable manner with yields up to 93% on a preparative scale under mild reaction conditions.
摘要
以KI为碘源、空气氧为氧化剂，漆酶催化的α-羟基芳基羰基和α-羟基芳基羧酸衍生物的碘化反应，在温和的反应条件下，以高效且可持续的方式得到相应的碘酚，在制备规模上产率高达93%。
Zotero 插件