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采用基于低共熔溶剂的电解质并抑制副产物形成的全固态可充电铝空气电池。

All solid state rechargeable aluminum-air battery with deep eutectic solvent based electrolyte and suppression of byproducts formation.

作者信息

Mori Ryohei

机构信息

Green Science Alliance Co., Ltd. 2-22-11 Obana Kawanishi City Hyogo Prefecture 666-0015 Japan.

Fuji Pigment Co. Ltd 2-23-2 Obana Kawanishi City Hyogo Prefecture 666-0015 Japan

出版信息

RSC Adv. 2019 Jul 17;9(39):22220-22226. doi: 10.1039/c9ra04567h.

DOI:10.1039/c9ra04567h
PMID:35519477
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9066622/
Abstract

In order to create a rechargeable aluminum (Al)-air battery, an aluminum-air battery with a deep eutectic solvent-based solid electrolyte was prepared. The prepared battery demonstrated a capacity smaller than the theoretical value although we observed stable electrochemical reactions. When TiN was used as an air cathode material, byproducts of the aluminum-air battery such as Al(OH) and AlO were not detected on either the Al anode nor the air cathode. Even though we did not detect byproducts, we observed NaCl and NHCl phases on the air cathode, and they did not hinder the electrochemical reaction.

摘要

为了制造一种可充电铝空气电池，制备了一种基于深共熔溶剂的固体电解质的铝空气电池。尽管观察到稳定的电化学反应，但所制备的电池容量小于理论值。当使用TiN作为空气阴极材料时，在铝阳极和空气阴极上均未检测到铝空气电池的副产物，如Al(OH)和AlO。即使未检测到副产物，我们在空气阴极上观察到了NaCl和NHCl相，并且它们并未阻碍电化学反应。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/142d/9066622/a28547076b67/c9ra04567h-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/142d/9066622/d55be76e89a7/c9ra04567h-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/142d/9066622/ad154bb68549/c9ra04567h-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/142d/9066622/1b8b9d71edd8/c9ra04567h-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/142d/9066622/333b1b95633d/c9ra04567h-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/142d/9066622/82e24dbb575e/c9ra04567h-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/142d/9066622/a28547076b67/c9ra04567h-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/142d/9066622/d55be76e89a7/c9ra04567h-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/142d/9066622/ad154bb68549/c9ra04567h-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/142d/9066622/1b8b9d71edd8/c9ra04567h-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/142d/9066622/333b1b95633d/c9ra04567h-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/142d/9066622/82e24dbb575e/c9ra04567h-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/142d/9066622/a28547076b67/c9ra04567h-f7.jpg

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