Yang Cao, Hassanpour Akbar, Ghorbanpour Khatereh, Abdolmohammadi Shahrzad, Vessally Esmail
School of Materials Science and Engineering, Zhengzhou University Zhengzhou 450001 China.
Department of Chemistry, Marand Branch, Islamic Azad University Marand Iran.
RSC Adv. 2019 Sep 3;9(47):27625-27639. doi: 10.1039/c9ra04170b. eCollection 2019 Aug 29.
The aim of this review is to provide a comprehensive overview of the direct trifluoromethylation of olefinic C-H bonds with special attention on the mechanistic aspects of the reactions. The review is divided into two major sections. The first focuses exclusively on trifluoromethylation of terminal alkenes, while the second will cover trifluoromethylation of internal alkenes. Literature has been surveyed until the end of April 2019.
本综述的目的是全面概述烯烃碳氢键的直接三氟甲基化反应,特别关注反应的机理方面。该综述分为两个主要部分。第一部分专门聚焦于末端烯烃的三氟甲基化反应,而第二部分将涵盖内烯烃的三氟甲基化反应。文献调研截至2019年4月底。