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中国成都污水处理厂中抗生素和重金属的存在与归宿及再生水风险评估。

Occurrence and fate of antibiotics and heavy metals in sewage treatment plants and risk assessment of reclaimed water in Chengdu, China.

机构信息

Department of Environmental Science and Engineering, College of Architecture and Environment Sichuan University, Chengdu, 610065, PR China.

出版信息

Chemosphere. 2021 Jun;272:129730. doi: 10.1016/j.chemosphere.2021.129730. Epub 2021 Feb 4.

Abstract

Aim of this study was to provide an up-to-date assessment of the heavy metals and antibiotics in reclaimed water in Chengdu, China. 3 sewage treatment plants (STPs) and 1 constructed wetland (CW) were first taken as the research objects. The total concentration and reduction change rule of heavy metals and antibiotics in the process of reclaimed water production were investigated. The possible health risks to ecological environment and human body were evaluated. For the treatment process, the Cyclic Activated Sludge System (CASS) used in A sewage treatment plant (STP A) had the best removal effect for heavy metals. When the proportion of industrial wastewater in the influent was relatively high, the heavy metal pollution level was alert. Ofloxacin (OFX) and roxithromycin (ROX) were the most abundant antibiotics in reclaimed water. After being removed by the sewage treatment system, OFX concentrations changed, but several of them remained in reclaimed water. Negative removal of ROX occurred. This is because macrolides were wrapped in human feces, whose concentration increased as feces disperse and hydrolyze. Compared with CASS (20.02%) and Anaerobic-Anoxic-Oxic process (A/O 34.16%), the average removal rate of antibiotics from the A/O accompanied by Membrane Bio-Reactor (71.1%) and CW (54.95%) was higher. When the proportion of domestic sewage in wastewater was high, antibiotics in reclaimed water had higher ecological risk. OFX had the highest ecological risk for non-target aquatic organisms. It was assessed that the heavy metals and antibiotics studied did not pose a carcinogenic or non-carcinogenic risk to human health.

摘要

本研究旨在对中国成都再生水中的重金属和抗生素进行最新评估。首先选择了 3 座污水处理厂(STP)和 1 座人工湿地(CW)作为研究对象。研究了再生水生产过程中重金属和抗生素的总量浓度变化规律及其去除规律,评估了其对生态环境和人体健康的潜在风险。对于处理工艺,A 污水处理厂(STP A)中使用的循环活性污泥系统(CASS)对重金属的去除效果最好。当进水工业废水比例较高时,重金属污染水平为警戒级。在再生水中,氧氟沙星(OFX)和罗红霉素(ROX)是最丰富的抗生素。经过污水处理系统的去除,OFX 的浓度发生了变化,但仍有几种存在于再生水中。ROX 发生了负去除。这是因为大环内酯类抗生素被包裹在人类粪便中,随着粪便的分散和水解,其浓度增加。与 CASS(20.02%)和厌氧-缺氧-好氧工艺(A/O 34.16%)相比,A/O 与膜生物反应器(71.1%)和 CW(54.95%)相结合的抗生素平均去除率更高。当污水中生活污水比例较高时,再生水中的抗生素具有更高的生态风险。OFX 对非目标水生生物的生态风险最高。评估认为,研究中的重金属和抗生素不会对人体健康造成致癌或非致癌风险。

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