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在聚醚砜混合基质膜中掺入氧化石墨烯以提高血液透析膜性能。

Incorporation of graphene oxide in polyethersulfone mixed matrix membranes to enhance hemodialysis membrane performance.

作者信息

Fahmi M Z, Wathoniyyah M, Khasanah M, Rahardjo Y, Wafiroh S

机构信息

Department of Chemistry, Universitas Airlangga Surabaya 61115 Indonesia

Institute of Tropical Disease, Airlangga University Surabaya 61115 Indonesia.

出版信息

RSC Adv. 2018 Jan 3;8(2):931-937. doi: 10.1039/c7ra11247e. eCollection 2018 Jan 2.

Abstract

Graphene is a carbon allotrope and possesses numerous unique properties which make it an attractive material in many areas. In this work, graphene oxide (GO) was added to polyethersulfone (PES) mixed matrix membranes (MMMs) to improve the performance of hemodialysis membranes. GO was synthesized from tartaric acid by pyrolysis with various temperatures of the pyrolysis and the membrane was fabricated by a casting solution method followed by its characterization. The MMMs showed better mechanical properties than pristine PES with a tensile stress and tensile strain value of 5.55 MPa and 0.039 m, respectively. The hydrophilicity of the membranes which is in agreement with contact angle values showed that GO addition increased the hydrophilicity of the MMMs. Hence, the solute flux and clearance of creatinine gave values of 2.94 L m h and 78.3%, respectively. Cross sectional images and the surface morphology were also recorded using scanning electron microscopy (SEM). The resulting data proved that the modified MMMs can be a potential material for hemodialysis.

摘要

石墨烯是一种碳的同素异形体,具有许多独特的性质,使其在许多领域成为一种有吸引力的材料。在这项工作中,将氧化石墨烯(GO)添加到聚醚砜(PES)混合基质膜(MMMs)中,以提高血液透析膜的性能。通过在不同热解温度下由酒石酸热解合成GO,并通过浇铸溶液法制备膜,随后对其进行表征。MMMs的机械性能优于原始PES,拉伸应力和拉伸应变值分别为5.55 MPa和0.039 m。与接触角值一致的膜的亲水性表明,添加GO增加了MMMs的亲水性。因此,肌酐的溶质通量和清除率分别为2.94 L m h和78.3%。还使用扫描电子显微镜(SEM)记录了横截面图像和表面形态。所得数据证明,改性后的MMMs可以成为血液透析的潜在材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12f5/9077013/bc88baf4313c/c7ra11247e-s1.jpg

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