Sun Shupei, Sun Yu, Wen Jiang, Zhang Bo, Liao Xiaoming, Yin Guangfu, Huang Zhongbing, Pu Ximing
College of Materials Science and Engineering, Sichuan University Chengdu Sichuan 610065 China
RSC Adv. 2018 Jun 13;8(39):21823-21828. doi: 10.1039/c8ra02744g.
Here we report the supercapacitive properties of a novel MoO /TiO nanotube composite prepared by a facile galvanostatic deposition technique and subsequently thermal treatment in an argon atmosphere between 350 °C and 550 °C. X-ray diffraction and X-ray photoelectron spectroscopy confirm the existence of MoO . The MoO /TiO electrode prepared at 550 °C exhibits a high specific capacitance of 23.69 mF cm at a scan rate of 10 mV s and good cycling stability with capacitance retention of 86.6% after 1000 cycles in 1 M NaSO aqueous solution. Our study reveals a feasible method for the fabrication of TiO nanotubes modified with electroactive MoO as high-performance electrode materials for supercapacitors.
在此,我们报告了一种新型MoO₂/TiO₂纳米管复合材料的超级电容特性,该复合材料通过简便的恒电流沉积技术制备,随后在350℃至550℃的氩气气氛中进行热处理。X射线衍射和X射线光电子能谱证实了MoO₂的存在。在550℃制备的MoO₂/TiO₂电极在扫描速率为10 mV s⁻¹时表现出23.69 mF cm⁻²的高比电容,并且具有良好的循环稳定性,在1 M Na₂SO₄水溶液中经过1000次循环后电容保持率为86.6%。我们的研究揭示了一种制备用具有电活性的MoO₂修饰的TiO₂纳米管作为超级电容器高性能电极材料的可行方法。