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一种在无催化剂和无氧化剂条件下用于富电子芳烃的低成本电化学硫氰化和硒氰化策略。

A low-cost electrochemical thio- and selenocyanation strategy for electron-rich arenes under catalyst- and oxidant-free conditions.

作者信息

Zhang Xing, Wang Chenguang, Jiang Hong, Sun Linhao

机构信息

Department of Chemistry, College of Science, Huazhong Agricultural University Wuhan 430070 P. R. China

出版信息

RSC Adv. 2018 Jun 14;8(39):22042-22045. doi: 10.1039/c8ra04407d. eCollection 2018 Jun 13.

DOI:10.1039/c8ra04407d
PMID:35541747
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9081088/
Abstract

A low-cost and efficient thio- and selenocyanation strategy for electron-rich arenes has been developed under constant-current electrolytic conditions in an undivided cell. This strategy is versatile for various (hetero)aromatic compounds such as indole, pyrrole, aniline and anisole under mild conditions without any catalyst or oxidant. Readily available salts NHSCN and KSeCN are employed respectively as the sole reagent.

摘要

在恒流电解条件下的无隔膜电解池中，已开发出一种用于富电子芳烃的低成本高效硫氰化和硒氰化策略。该策略在温和条件下，无需任何催化剂或氧化剂，对各种（杂）芳族化合物，如吲哚、吡咯、苯胺和苯甲醚都具有通用性。分别使用易于获得的盐NHSCN和KSeCN作为唯一试剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88eb/9081088/249f3fed4437/c8ra04407d-s5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88eb/9081088/4ec3934478d4/c8ra04407d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88eb/9081088/4e8d285613dc/c8ra04407d-s1.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88eb/9081088/af54af0107af/c8ra04407d-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88eb/9081088/5a3d52ae837f/c8ra04407d-s4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88eb/9081088/249f3fed4437/c8ra04407d-s5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88eb/9081088/4ec3934478d4/c8ra04407d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88eb/9081088/4e8d285613dc/c8ra04407d-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88eb/9081088/692327b48db2/c8ra04407d-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88eb/9081088/af54af0107af/c8ra04407d-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88eb/9081088/5a3d52ae837f/c8ra04407d-s4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/88eb/9081088/249f3fed4437/c8ra04407d-s5.jpg

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