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具有光致发光和顺磁特性的三维铽掺杂还原氧化石墨烯气凝胶的制备。

The preparation of a three dimensional terbium doped reduced graphene oxide aerogel with photoluminescence and paramagnetic properties.

作者信息

Chen Keqin, Gao Hui, Wang Dongdong, Li Xiaolong, Wang Deying, Khan Waheed Ullah

机构信息

School of Physical Science and Technology, Key Laboratory for Magnetism and Magnetic Materials of Ministry of Education, Lanzhou University Lanzhou 730000 P. R. China

National & Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, Key Laboratory of Special Function Materials and Structure Design, Ministry of Education P. R. China.

出版信息

RSC Adv. 2018 Mar 5;8(17):9287-9292. doi: 10.1039/c7ra12087g. eCollection 2018 Feb 28.

Abstract

A 3D reduced graphene oxide (rGO) material with good photoluminescence (PL) and magnetism properties was self-assembled using the hydrothermal method. The resultant material possessed a flower-like structure, which leads to a high surface area. To dehydrate the hydrogel for conservation, the sublimation process we use can effectively maintain the porosity as it uses the freeze drying method. Then, rGO was endowed with paramagnetism and green photoluminescence properties the introduction of Tb ions, which also reinforces the significance of the building block. Finally, the coordination between Tb ions and the carbonyl was proven with photoluminescence excitation (PLE) spectra and the UV-vis absorption spectra, which are likely to offer an effective way to study the carbonyl compound.

摘要

采用水热法自组装了一种具有良好光致发光(PL)和磁性的三维还原氧化石墨烯(rGO)材料。所得材料具有花状结构,这导致了高表面积。为了对水凝胶进行脱水保存,我们采用的升华过程可以有效地保持孔隙率,因为它使用了冷冻干燥法。然后,通过引入Tb离子,rGO被赋予了顺磁性和绿色光致发光特性,这也增强了构建单元的重要性。最后,通过光致发光激发(PLE)光谱和紫外可见吸收光谱证明了Tb离子与羰基之间的配位作用,这可能为研究羰基化合物提供一种有效的方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2181/9078696/673f5481fe0c/c7ra12087g-f1.jpg

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