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利用水果提取物在还原氧化石墨烯上负载钯纳米颗粒的绿色合成方法,以及它们作为可回收的多相纳米催化剂用于降解水中染料污染物的应用。

Green synthesis of Pd nanoparticles supported on reduced graphene oxide, using the extract of fruit, and their use as recyclable and heterogeneous nanocatalysts for the degradation of dye pollutants in water.

作者信息

Hemmati Saba, Mehrazin Lida, Ghorban Hedieh, Garakani Samir Hossein, Mobaraki Taha Hashemi, Mohammadi Pourya, Veisi Hojat

机构信息

Department of Pharmaceutical Chemistry, Faculty of Pharmaceutical Chemistry, Pharmaceutical Sciences Branch, Islamic Azad University, (IAUPS) Tehran Iran.

Department of Chemistry, Payame Noor University Tehran Iran

出版信息

RSC Adv. 2018 Jun 7;8(37):21020-21028. doi: 10.1039/c8ra03404d. eCollection 2018 Jun 5.

Abstract

The current study suggests a convenient synthesis of , ecofriendly and well-dispersed palladium nanoparticles with narrow and small dimension distributions on a graphene oxide (GO) surface using a fruit extract as a stabilizer and reducing agent without the addition of any other stabilizers or surfactants. The as-synthesized nanocatalyst (Pd NPs/RGO) was assessed with XRD, UV-vis, FE-SEM, EDS, TEM, ICP and WDX. The obtained heterogeneous nanocatalyst showed catalytic performance for reducing 4-nitrophenol (4-NP), rhodamine B (RhB) and methylene blue (MB) at ambient temperature in an ecofriendly medium. The catalyst was retained by centrifugation and reused several times with no considerable change in its catalytic performance.

摘要

当前的研究表明,使用水果提取物作为稳定剂和还原剂,无需添加任何其他稳定剂或表面活性剂,即可在氧化石墨烯(GO)表面方便地合成尺寸分布窄且小、环保且分散良好的钯纳米颗粒。通过XRD、紫外可见光谱、场发射扫描电子显微镜、能谱分析、透射电子显微镜、电感耦合等离子体质谱和波长色散X射线光谱对合成的纳米催化剂(Pd NPs/RGO)进行了评估。所获得的多相纳米催化剂在环境温度下的环保介质中表现出对4-硝基苯酚(4-NP)、罗丹明B(RhB)和亚甲基蓝(MB)的催化还原性能。该催化剂通过离心得以保留,并可重复使用多次,其催化性能没有显著变化。

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