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具有高度有序孔排列的纳米多孔氧化铝空心球的制备。

Preparation of nanoporous alumina hollow spheres with a highly ordered hole arrangement.

作者信息

Yanagishita Takashi, Imaizumi Masahiko, Kondo Toshiaki, Masuda Hideki

机构信息

Department of Applied Chemistry, Tokyo Metropolitan University 1-1 Minamiosawa, Hachioji Tokyo 192-0397 Japan

出版信息

RSC Adv. 2018 Jan 9;8(4):2041-2047. doi: 10.1039/c7ra12340j. eCollection 2018 Jan 5.

DOI:10.1039/c7ra12340j
PMID:35542576
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9077359/
Abstract

Nanoporous alumina spheres with an ordered hole arrangement were prepared through a two-step anodization of small Al particles. The hole periodicity in the ordered anodic porous alumina could be controlled by adjusting the anodizing conditions. Nanoporous hollow spheres were also obtained by removal of residual Al in an etchant. Additionally, nanoporous spheres loaded with Au nanoparticles on their surfaces were obtained through electrochemical or chemical deposition of Au nanoparticles. The obtained Au/alumina composite hollow spheres were used as a substrate for surface-enhanced Raman scattering measurements.

摘要

通过对小铝颗粒进行两步阳极氧化制备了具有有序孔排列的纳米多孔氧化铝球。有序阳极多孔氧化铝中的孔周期可以通过调整阳极氧化条件来控制。通过在蚀刻剂中去除残留的铝,还获得了纳米多孔空心球。此外,通过金纳米颗粒的电化学或化学沉积,在其表面负载金纳米颗粒的纳米多孔球也得以制备。所制备的金/氧化铝复合空心球用作表面增强拉曼散射测量的基底。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/e88e664e77c1/c7ra12340j-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/b99e6977f3b2/c7ra12340j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/7f8ff4f389fb/c7ra12340j-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/2de8fdeac8c5/c7ra12340j-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/877c1b554153/c7ra12340j-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/c880a66d6197/c7ra12340j-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/b967ab3ebd06/c7ra12340j-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/3f1431468912/c7ra12340j-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/9005b27330c3/c7ra12340j-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/f70c61f4161f/c7ra12340j-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/e88e664e77c1/c7ra12340j-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/b99e6977f3b2/c7ra12340j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/7f8ff4f389fb/c7ra12340j-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/2de8fdeac8c5/c7ra12340j-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/877c1b554153/c7ra12340j-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/c880a66d6197/c7ra12340j-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/b967ab3ebd06/c7ra12340j-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/3f1431468912/c7ra12340j-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/9005b27330c3/c7ra12340j-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/f70c61f4161f/c7ra12340j-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f7c/9077359/e88e664e77c1/c7ra12340j-f10.jpg

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