Transition metal oxides are commonly used in electrochemical energy storage materials, but there are still many drawbacks that impede a wide range of applications. Heteroatom doping can significantly improve its performance. Herein, we have successfully prepared highly uniform N-doped NiCoO@C hollow nanostructures for supercapacitors by a two-step hydrothermal treatment associated with successive annealing process. Prepared N-doped NiCoO@C materials exhibited an admirable specific capacitance of 1028 F g at a current density of 3 A g, with 625 F g remaining even at high current density of 20 A g. Besides, this composite showed good electrochemical stability with capacity retention of 84% after 5000 cycles repetitive galvanostatic charge-discharge test at 10 A g. An asymmetric supercapacitor was assembled by the N-doped NiCoO@C electrode, attached activate carbon (AC) as a counter electrode, exhibiting a high energy density of 26.67 W h kg at a power density of 402 W kg. The improvement of electrochemical performance is ascribed to the co-doping of nitrogen and carbon atoms. These results indicate that N-doped NiCoO@C can be employed as an ideal electrode material for electrochemical energy storage.