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以泡沫镍上的芽状铜掺杂二氧化锰空心多孔结构作为正极的不对称超级电容器的性能增强

Performance enhancement of asymmetric supercapacitors with bud-like Cu-doped MnO hollow and porous structures on nickel foam as positive electrodes.

作者信息

Chen Xiaobo, Chen Cheng, Xu Tianzhi, Xu Yingjie, Liu Weiwei, Yang Wen, Yang Peizhi

机构信息

School of New Energy and Electronic Engineering, Yancheng Teachers University Yancheng 224051 PR China.

Key Laboratory of Education Ministry for Advance Technique and Preparation of Renewable Energy Materials, Yunnan Normal University Kunming 650500 PR China

出版信息

RSC Adv. 2018 Oct 22;8(63):35878-35887. doi: 10.1039/c8ra06989a.

Abstract

Cu-doped MnO hollow nanostructures supported on Ni foams as high-performance electrode materials for supercapacitors were successfully synthesized through a facile hydrothermal method and subsequent calcination. The morphology, structure, and electrochemical performance of the as-prepared MnO nanostructures can be tuned just by varying the Cu doping content. Benefiting from the unique bud-like hollow structure, the 1.5 at% Cu-doped MnO sample has a high specific capacitance of 257.6 F g at 1 A g and remarkable stability (about 90.6% retention of its initial capacitance after 6000 electrochemical cycles). Besides, an asymmetric supercapacitor (ASC) cell based on the 1.5 at% Cu-doped MnO exhibits a high specific capacitance of 305.6 F g at 1 A g and an energy density of 108.6 W h kg at a power density of 799.9 W kg. More importantly, the ASC shows good long-term stability with 86.9% capacity retention after charging/discharging for 6000 cycles at a high current density of 5 A g.

摘要

通过简便的水热法和后续煅烧,成功合成了负载在泡沫镍上的铜掺杂二氧化锰空心纳米结构,作为超级电容器的高性能电极材料。仅通过改变铜掺杂含量,就可以调节所制备的二氧化锰纳米结构的形貌、结构和电化学性能。得益于独特的芽状空心结构,1.5原子百分比铜掺杂的二氧化锰样品在1 A g时具有257.6 F g的高比电容和出色的稳定性(在6000次电化学循环后约保留其初始电容的90.6%)。此外,基于1.5原子百分比铜掺杂二氧化锰的不对称超级电容器(ASC)电池在1 A g时具有305.6 F g的高比电容,在799.9 W kg的功率密度下能量密度为108.6 W h kg。更重要的是,该ASC在5 A g的高电流密度下充放电6000次后,容量保持率为86.9%,显示出良好的长期稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/702b/9088714/3b020dc13f9a/c8ra06989a-f1.jpg

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