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利用细菌生物膜废弃物水热制备氧化铁作为新型纳米材料用于广泛应用。

The hydrothermal processing of iron oxides from bacterial biofilm waste as new nanomaterials for broad applications.

作者信息

Yu Le, Tran Diana N H, Forward Peter, Lambert Martin F, Losic Dusan

机构信息

School of Chemical Engineering, The University of Adelaide Adelaide SA 5005 Australia

ARC Graphene Enabled Industry Transformation Hub, The University of Adelaide Adelaide SA 5005 Australia.

出版信息

RSC Adv. 2018 Oct 11;8(61):34848-34852. doi: 10.1039/c8ra07061j. eCollection 2018 Oct 10.

Abstract

Iron oxides and their hydroxides have been studied and analysed with properties of their mutual transformations under different hydrothermal conditions being indicated. Amorphous bacteria nanowires produced from biofilm waste were investigated under the influence of pH at a fixed duration (20 h) and reaction temperature (200 °C). The morphology, structure, and particle size of the transformation of hematite (α-FeO) was obtained and characterised with SEM, XRD, FTIR, and particle sizer. The optimal conditions for the complete conversion of amorphous iron oxide nanowires to crystalline α-FeO is under acidic conditions where the pH is 1. The flower-like α-FeO structures have photocatalytic activity and adsorbent properties for heavy metal ions. This one-pot synthesis approach to produce α-FeO at a low cost would be greatly applicable to the recycling process of biofilm waste in order to benefit the environment.

摘要

对氧化铁及其氢氧化物进行了研究和分析,并指出了它们在不同水热条件下相互转化的性质。在固定时长(20小时)和反应温度(200℃)下,研究了生物膜废料产生的无定形细菌纳米线在pH值影响下的情况。通过扫描电子显微镜(SEM)、X射线衍射仪(XRD)、傅里叶变换红外光谱仪(FTIR)和粒度分析仪获得并表征了赤铁矿(α-FeO)转变的形态、结构和粒径。将无定形氧化铁纳米线完全转化为结晶α-FeO的最佳条件是在pH值为1的酸性条件下。花状α-FeO结构对重金属离子具有光催化活性和吸附性能。这种低成本一锅法合成α-FeO的方法将非常适用于生物膜废料的回收过程,以造福环境。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4216/9087643/445b4cd8e9f8/c8ra07061j-f1.jpg

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