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通过电沉积在泡沫镍上生长的钴锰镍硫化物（CoMnNiS）纳米片的赝电容电池样行为，以实现高容量。

Pseudocapacitive-battery-like behavior of cobalt manganese nickel sulfide (CoMnNiS) nanosheets grown on Ni-foam by electrodeposition for realizing high capacity.

作者信息

Verma Mahesh, Yadav Rohit, Sinha Lichchhavi, Mali Sawanta S, Hong Chang Kook, Shirage Parasharam M

机构信息

Discipline of Metallurgy Engineering and Material Science, Indian Institute of Technology Indore Khandwa Road, Simrol Indore-453552 India

Discipline of Physics, Indian Institute of Technology Indore Indore-453552 India.

出版信息

RSC Adv. 2018 Nov 30;8(70):40198-40209. doi: 10.1039/c8ra07471b. eCollection 2018 Nov 28.

DOI:10.1039/c8ra07471b
PMID:35558247
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9091183/
Abstract

Hierarchical interconnected nanosheets (HIN) of cobalt manganese nickel sulfide (CoMnNiS) were synthesized on Ni foam by a simple and economical electrodeposition technique for energy storage application. Sulfonated thin nanosheets of Co, Mn and Ni provide stability of chemical activity, surface functionalization and surface reactivity to the electrode. The fabricated electrode shows a specific capacity of 257.4 mA h g (at 2.5 A g), measured by galvanostatic charging-discharging (GCD). Both diffusion and capacitive mechanisms in the sulfide layer contribute to the high electrical conductivity. Asymmetric devices CoMnNiS/NiCuO and CoMnNiS/CNT (CNT = carbon nanotubes) were fabricated, providing a maximum operating voltage of 1.7 V and 1 V, specific capacity of 20.8 and 50.8 mA h g, and energy density of 8.4 and 6.3 W h kg corresponding to a power density of 985 and 211 W kg, respectively, at a current density of 0.5 and 0.63 A g. These results demonstrate a novel material for application in energy storage devices as an electrode.

摘要

通过一种简单且经济的电沉积技术，在泡沫镍上合成了用于储能应用的硫化钴锰镍（CoMnNiS）分层互连纳米片（HIN）。钴、锰和镍的磺化薄纳米片为电极提供了化学活性稳定性、表面功能化和表面反应性。通过恒电流充放电（GCD）测量，制备的电极在2.5 A g时的比容量为257.4 mA h g。硫化物层中的扩散和电容机制都有助于提高电导率。制备了不对称器件CoMnNiS/NiCuO和CoMnNiS/CNT（CNT = 碳纳米管），在电流密度为0.5和0.63 A g时，其最大工作电压分别为1.7 V和1 V，比容量分别为20.8和50.8 mA h g，能量密度分别为8.4和6.3 W h kg，对应的功率密度分别为985和211 W kg。这些结果证明了一种作为电极应用于储能器件的新型材料。

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J Nanosci Nanotechnol. 2017 Feb;17(2):1387-392. doi: 10.1166/jnn.2017.12666.
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