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过渡金属氧化物作为不可或缺的钠离子电池的阴极。

Transition metal oxides as a cathode for indispensable Na-ion batteries.

作者信息

Kanwade Archana, Gupta Sheetal, Kankane Akash, Tiwari Manish Kumar, Srivastava Abhishek, Kumar Satrughna Jena Akash, Chand Yadav Subhash, Shirage Parasharam M

机构信息

Department of Metallurgy Engineering and Materials Science, Indian Institute of Technology Indore 453552 India

Department of Physics, Indian Institute of Technology Indore 453552 India.

出版信息

RSC Adv. 2022 Aug 17;12(36):23284-23310. doi: 10.1039/d2ra03601k. eCollection 2022 Aug 16.

DOI:10.1039/d2ra03601k
PMID:36090429
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9382698/
Abstract

The essential requirement to harness well-known renewable energy sources like wind energy, solar energy, . as a component of an overall plan to guarantee global power sustainability will require highly efficient, high power and energy density batteries to collect the derived electrical power and balance out variations in both supply and demand. Owing to the continuous exhaustion of fossil fuels, and ever increasing ecological problems associated with global warming, there is a critical requirement for searching for an alternative energy storage technology for a better and sustainable future. Electrochemical energy storage technology could be a solution for a sustainable source of clean energy. Sodium-ion battery (SIB) technology having a complementary energy storage mechanism to the lithium-ion battery (LIB) has been attracting significant attention from the scientific community due to its abundant resources, low cost, and high energy densities. Layered transition metal oxide (TMO) based materials for SIBs could be a potential candidate for SIBs among all other cathode materials. In this paper, we discussed the latest improvement in the various structures of the layered oxide materials for SIBs. Moreover, their synthesis, overall electrochemical performance, and several challenges associated with SIBs are comprehensively discussed with a stance on future possibilities. Many articles discussed the improvement of cathode materials for SIBs, and most of them have pondered the use of Na MO (a class of TMOs) as a possible positive electrode material for SIBs. The different phases of layered TMOs (Na MO; TM = Co, Mn, Ti, Ni, Fe, Cr, Al, V, and a combination of multiple elements) show good cycling capacity, structural stability, and Na ion conductivity, which make them promising cathode material for SIBs. This review discusses and summarizes the electrochemical redox reaction, structural transformations, significant challenges, and future prospects to improve for Na MO. Moreover, this review highlights the recent advancement of several layered TMO cathode materials for SIBs. It is expected that this review will encourage further development of layered TMOs for SIBs.

摘要

将风能、太阳能等知名可再生能源作为保障全球电力可持续性整体计划的一部分加以有效利用，需要高效、高功率和高能量密度的电池来收集产生的电能，并平衡供需变化。由于化石燃料的不断枯竭以及与全球变暖相关的生态问题日益严重，迫切需要寻找一种替代储能技术，以实现更美好、更可持续的未来。电化学储能技术可能是实现可持续清洁能源的一种解决方案。钠离子电池（SIB）技术具有与锂离子电池（LIB）互补的储能机制，因其资源丰富、成本低和能量密度高而受到科学界的广泛关注。在所有其他阴极材料中，基于层状过渡金属氧化物（TMO）的材料可能是SIB的潜在候选材料。在本文中，我们讨论了用于SIB的层状氧化物材料各种结构的最新改进。此外，还从未来可能性的角度全面讨论了它们的合成、整体电化学性能以及与SIB相关的若干挑战。许多文章讨论了SIB阴极材料的改进，其中大多数都考虑将NaMO（一类TMO）用作SIB可能的正极材料。层状TMO的不同相（NaMO；TM = Co、Mn、Ti、Ni、Fe、Cr、Al、V以及多种元素的组合）表现出良好的循环容量、结构稳定性和Na离子传导性，这使其成为SIB有前景的阴极材料。本综述讨论并总结了NaMO的电化学氧化还原反应、结构转变、重大挑战和未来改进前景。此外，本综述突出了几种用于SIB的层状TMO阴极材料的最新进展。预计本综述将鼓励用于SIB的层状TMO的进一步发展。

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