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具有AlN层的n型氮化镓上原子层沉积氧化钆的特性

Characteristics of atomic layer deposited GdO on n-GaN with an AlN layer.

作者信息

Kim Hogyoung, Yun Hee Ju, Choi Byung Joon

机构信息

Department of Visual Optics, Seoul National University of Science and Technology (Seoultech) Seoul 01811 Republic of Korea

Departmet of Materials Science and Engineering, Seoul National University of Science and Technology (Seoultech) Seoul 01811 Republic of Korea

出版信息

RSC Adv. 2018 Dec 19;8(74):42390-42397. doi: 10.1039/c8ra09708a.

DOI:10.1039/c8ra09708a
PMID:35558409
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9092257/
Abstract

The interfacial and electrical properties of atomic layer deposited GdO with an AlN layer on n-GaN were investigated. According to X-ray photoelectron spectroscopy spectra, the formation of Ga-O bonds that is significant near the GdO/GaN interface was suppressed near the AlN/GdO/GaN and GdO/AlN/GaN interfaces. Larger amounts of oxygen atoms across the dielectric layers were observed for AlN/GdO/GaN and GdO/AlN/GaN junctions, which in turn produced the dominant peak corresponding to O-Al bonds. The flatband voltage shift in capacitance-voltage hysteresis characteristics was highest for the GdO/AlN/GaN junction, indicating the highest interface and oxide trap densities. In addition, AlN/GdO/GaN and GdO/AlN/GaN junctions showed the highest interface state densities in the energy ranges of 0.1-0.2 eV and 0.4-0.6 eV, respectively. The reverse leakage currents were explained by Fowler-Nordheim (FN) for GdO/GaN and AlN/GdO/GaN junctions and by trap assisted tunneling (TAT) for the GdO/AlN/GaN junction.

摘要

研究了在n型氮化镓上原子层沉积的氧化钆与氮化铝层的界面和电学性质。根据X射线光电子能谱,在氮化铝/氧化钆/氮化镓和氧化钆/氮化铝/氮化镓界面附近,抑制了在氧化钆/氮化镓界面附近显著形成的镓-氧键。对于氮化铝/氧化钆/氮化镓和氧化钆/氮化铝/氮化镓结,在介电层中观察到大量的氧原子,这反过来产生了对应于O-Al键的主峰。氧化钆/氮化铝/氮化镓结在电容-电压滞后特性中的平带电压偏移最高,表明界面和氧化物陷阱密度最高。此外,氮化铝/氧化钆/氮化镓和氧化钆/氮化铝/氮化镓结分别在0.1-0.2 eV和0.4-0.6 eV的能量范围内显示出最高的界面态密度。氧化钆/氮化镓和氮化铝/氧化钆/氮化镓结的反向漏电流由福勒-诺德海姆(FN)解释,而氧化钆/氮化铝/氮化镓结的反向漏电流由陷阱辅助隧穿(TAT)解释。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/364dec6a70f8/c8ra09708a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/c5534b36b3c8/c8ra09708a-f1.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/bfefe4413799/c8ra09708a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/9535bc4a6ef9/c8ra09708a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/ad4f1a7c5294/c8ra09708a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/48032d37ce41/c8ra09708a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/364dec6a70f8/c8ra09708a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/c5534b36b3c8/c8ra09708a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/70cb57b8a086/c8ra09708a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/1ba694112868/c8ra09708a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/bfefe4413799/c8ra09708a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/9535bc4a6ef9/c8ra09708a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/ad4f1a7c5294/c8ra09708a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/48032d37ce41/c8ra09708a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e3/9092257/364dec6a70f8/c8ra09708a-f8.jpg

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本文引用的文献

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Investigation of the Structural, Electrical, and Optical Properties of the Nano-Scale GZO Thin Films on Glass and Flexible Polyimide Substrates.玻璃和柔性聚酰亚胺衬底上纳米级GZO薄膜的结构、电学和光学性质研究。
Nanomaterials (Basel). 2016 May 10;6(5):88. doi: 10.3390/nano6050088.
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Surface chemistry of rare-earth oxide surfaces at ambient conditions: reactions with water and hydrocarbons.
常温条件下稀土氧化物表面的表面化学:与水和碳氢化合物的反应。
Sci Rep. 2017 Mar 22;7:43369. doi: 10.1038/srep43369.
4
Impacts of Thermal Atomic Layer-Deposited AlN Passivation Layer on GaN-on-Si High Electron Mobility Transistors.热原子层沉积AlN钝化层对硅基氮化镓高电子迁移率晶体管的影响
Nanoscale Res Lett. 2016 Dec;11(1):137. doi: 10.1186/s11671-016-1335-7. Epub 2016 Mar 10.